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Sulfonated polyetherketone (SPEK-C) films investigated by positron annihilation lifetime spectroscopy and atomic force microscopy

LOW ENERGY ACCELERATOR, RAY TECHNOLOGY AND APPLICATIONS

Sulfonated polyetherketone (SPEK-C) films investigated by positron annihilation lifetime spectroscopy and atomic force microscopy

Htwe Htwe Yin
YIN Ze-Jie
TANG Shi-Biao
HUANG Huan
ZHU Da-Ming
Nuclear Science and TechniquesVol.16, No.6pp.341-346Published in print 01 Dec 2005
26900

The characterization of sulfonated polyetherketone (SPEK-C) films was investigated by using positron annihilation lifetime spectroscopy (PALS) and atomic force microscopy (AFM). It was found that free volume radius and intensity depend on the variation of sulfonation degree and solvent evaporation time of the films. Pore size and distribution determined from PALS and AFM measurements showed reasonable agreement.

Atomic force microscopy (AFM)Sulfonated polyetherketone (SPEK-C)Sulfonation degreePositron lifetimeFree volumePore size
References
[1] Jean Y C, NATO Advanced Research Workshop, 1993: 563-580
[2] Dlubek G, Stejny J, Lupke T H, et al. J Polym Sci, 2002, B40: 65-81
[3] Binnig G, Quate C F, Gerber C. Phys Rev Lett, 1986, 56: 930
[4] Kim J Y, Lee H K, Kim S C. J Membr Sci, 1999, 163: 159-166
[5] Trotta F, Drioli E, Moraglio G, et al. J Appl Polym Sci, 1998, 70: 477
[6] Colquhoun H M, Lewis D F, Herbertson P L, et al. Polymer, 1997, 38: 4539
[7] Jia L D, Xu X F, Zhang H J, et al. J Appl Polym Sci, 1996, 60: 1231
[8] Hu K, Xu T W, Fu Y X, et al. J Appl Polym Sci, 2004, 92: 1478
[9] Kirkegaard P, Pedersen N J, Eldrup M. PATFIT-88. Risoe National Laboratory, Roskilde, Denmark, 1989.
[10] Tao S J. J Chem Phys, 1972, 56: 5499
[11] Eldrup M, Lightbody D, Sherwood J N. Chem Phys, 1981, 63: 51
[12] Nakanishi H, Wang S J, Jean Y C. In Positron annihilation studies of fluids, Sharma S C, (Ed.) Singapore: World Science, 1988: 292
[13] Wang Y Y, Nakanishi H, Jean Y C, et al. J Polym Sci, 1990, B28: 1431
[14] PSIA Corp., Available from: http://www.psia.co.kr