logo

The synergic extraction of uranium (VI) with tri-n-butyl phosphate (TBP) and petroleum sulfoxides(PSO)/benzene

The synergic extraction of uranium (VI) with tri-n-butyl phosphate (TBP) and petroleum sulfoxides(PSO)/benzene

DONG Yan
YANG Yan-Zhao
FAN Wei-Liu
SUN Si-Xiu
Nuclear Science and TechniquesVol.12, No.4pp.270-275Published in print 01 Nov 2001
37500

The synergistic extraction of uranium (VI) from nitric acid aqueous solution with a mixture of tri-n-butyl phosphate (TBP) and petroleum sulfoxides(PSO) in benzene was studied. It has been found that the maximum synergistic extraction effect occurs where the molar ratio of PSO to TBP is one to two. The composition of the complex of synergistic extraction is UO2(NO3)2·TBP·PSO. The formation constant of the complex KTP=57.44.

Tri-n-butyl phosphatePetroleum sulfoxidesSynergistic extractionUranium (VI)
References
1 Cotton F A, Francis R. J Am Chem Soc, 1960, 82: 2986
2 Yang Y Z, Sun S X, Lei Z et al. J Radioanal Nucl Chem, 1999, 240: 383
3 Yang Y Z, Sun G X, Bao B R et al. Nucl Sci Tech, 1998, 9(3): 163
4 Chakravortty V, Dash K C, Mohanty s R. Radiochim Acta, 1986, 40: 89
5 Shen C H, Bao B R, Bao Y Z et al. J Radioanal And Nucl Chem, 1994, 178: Articles 91
6 Yang Y Z, Yang Y H, Jiang X C et al. J Radioanal Nucl Chem. 1999, 240: 335
7 Wang J H, Zhou Z M, Xu D M. Nucl Chem Radiochem (in Chinese), 1992, 14:(4): 226
8 Dong L Y, Analytical chemistry of uranium (in Chinese). Beijing: Atomic Energy Publishing, 1982, 158