Extraction study of rare earth elements with N,N′-dibutyl –N,N′-di(1-methylheptyl)-diglycolamide from hydrochloric acid

Guo-Jing Sun; Jin-Hong Yang; Hong-Xiao Yang; Guo-Xin Sun; Yu Cui

doi:10.1007/s41365-016-0055-0

Your Location：

Home >

Browse articles >

Extraction study of rare earth elements with N,N′-dibutyl –N,N′-di(1-methylheptyl)-diglycolamide from hydrochloric acid

NUCLEAR CHEMISTRY, RADIOCHEMISTRY, RADIOPHARMACEUTICALS AND NUCLEAR MEDICINE | Updated：2021-02-23

- Extraction study of rare earth elements with N,N′-dibutyl –N,N′-di(1-methylheptyl)-diglycolamide from hydrochloric acid
- Nuclear Science and Techniques Vol. 27, Issue 3, Article number: 75(2016)
- Affiliations：
  
  1.School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022, China
- Author bio：
  
  Corresponding author Email: chm_cuiy@ujn.edu.cn
- Funds：
- DOI：10.1007/s41365-016-0055-0
  CLC：
Scan for full text
Guo-Jing Sun, Jin-Hong Yang, Hong-Xiao Yang, et al. Extraction study of rare earth elements with N,N′-dibutyl –N,N′-di(1-methylheptyl)-diglycolamide from hydrochloric acid. [J]. Nuclear Science and Techniques 27(3):75(2016)
DOI：

Guo-Jing Sun, Jin-Hong Yang, Hong-Xiao Yang, et al. Extraction study of rare earth elements with N,N′-dibutyl –N,N′-di(1-methylheptyl)-diglycolamide from hydrochloric acid. [J]. Nuclear Science and Techniques 27(3):75(2016) DOI： 10.1007/s41365-016-0055-0.

摘要

Abstract

A novel, unsymmetrical diglycolamide, N,N′-dibutyl –N,N’-di(1-methylheptyl)-diglycolamide (DBD1MHDGA), was synthesized. The extraction of rare earth elements (REEs) from a hydrochloric acid medium with DBD1MHDGA was investigated. The results of the extraction experiments indicated that the distribution ratios of RE (III) ions increase with an increase in HCl concentration, atomic number, and extractant concentration. The calculated thermodynamic data shows that the extraction process is an exothermic reaction. The organic phase loaded rare earth ions were characterized by infrared spectroscopy. The composition of the extracted complex was determined.

关键词

Keywords

extractionrare earthhydrochloric acidDBD1MHDGA.

references

M.E. Nasab, A. Sam, S.A. Milani, Determination of optimum process conditions for the separation of thorium and rare earth elements by solvent extraction. Hydrometallurgy. 106, 141-147 (2011). doi: 10.1016/j.hydromet.2010.12.014http://doi.org/10.1016/j.hydromet.2010.12.014.

D.A. Renata, A.M. Carlos, Study on separation of heavy rare earth elements by solvent extraction with organophosphorus acids and amine reagents. Eng. 61, 82-87 (2014). doi: 10.1016/j.mineng.2014.03.015http://doi.org/10.1016/j.mineng.2014.03.015.

S. Radhika, K.B. Nagaphani, K.M. Lakshmi, Solvent extraction an separation of rare-earths from phosphoric acid solutions with TOPS 99. Hydrometallurgy. 110, 50-55 (2011). doi: 10.1016/j.hydromet.2011.08004http://doi.org/10.1016/j.hydromet.2011.08004.

B.C. McLellan, G.D. Corder, A. Golev, S.H. Ali, Sustainability of the Rare Earths Industry. Proc. Environ. Sci. 20, 280-287 (2014). doi: 10.1016/j.proenv.2014.03.035http://doi.org/10.1016/j.proenv.2014.03.035

Q. Jia, S.S. Tong, Z.Y. Li et al., Solvent extraction of rare earth elements with mixtures of sec-octylphenoxy acetic acid and bis(2,4,4-trimethylpentyl) dithiophosphinic acid. Sep. Purif. Technol. 64, 345-350 (2009). doi: 10.1016/j.seppur.2008.10.024http://doi.org/10.1016/j.seppur.2008.10.024

C.Z. Li, C.F. Yao, S.B. Wang, Z.X. Jia, C.F. He, D. Zhao, G.S. Qin, W.P. Qin, Tm3+/Ho3+ co-doped fluorotellurite microstructure fiber for 2.1 μm lasing. Chinese J. Luminescence. 37, 74-80 (2016). doi: 3788/fgxb20163701.0074http://doi.org/3788/fgxb20163701.0074

P.Z. Hu, L.J. Qian, H.L. Wang et al., Extraction of uranium(VI) and thorium(IV) from nitric acid solution by N,N,N′,N′ - tetraoctylglutaricamide. Sep. Sci. Technol. 49, 1521-1526 (2014). doi: 10.1080/01496395.2014.885531http://doi.org/10.1080/01496395.2014.885531

H. Tong, Y.L. Wang, W.P. Liao et al., Synergistic extraction of Ce(IV) and Th(IV) with mixtures of Cyanex 923 and organophosphorus acids in sulfuric acid media. Sep. Purif. Technol. 118, 487-491 (2014). doi: 10.1016/j.seppur.2013.07.039http://doi.org/10.1016/j.seppur.2013.07.039

W.H. Duan, P.J. Cao, Y.J. Zhu, Extraction of rare earth elements from their oxides using organophosphorus reagent complexes with HNO3 and H2O in supercritical CO2. Rare Earths. 28, 221-226 (2010). doi: 10.1016/S1002-0721(09)60084-3http://doi.org/10.1016/S1002-0721(09)60084-3

M.M. Tian, Q. Jia, W.P. Liao, Studies on synergistic solvent extraction of rare earth elements from nitrate medium by mixtures of 8-hydroxyquinoline with Cyanex 301 or Cyanex 302. J. Rare Earths. 31, 604-608 (2013). doi: 10.1016/S1002-0721(12)60328-7http://doi.org/10.1016/S1002-0721(12)60328-7

R. Surampally, N.K. Batchu, L.K. Mannepalli et al., Studies on solvent extraction of Dy(III) and separation possibilities of rare earths using PC-88A from phosphoric acid solutions. J. Taiwan Inst. Chem. Eng. 43, 839-844 (2012). doi: 10.1016/j.jtice.2012.04.009http://doi.org/10.1016/j.jtice.2012.04.009

H. Huang, S.D. Ding, N. Liu et al., Extraction of trivalent americium and europium from nitric acid solution with a calixarene-based diglycolamide. Sep. Purif. Technol. 123, 235-240 (2014). doi: 10.1016/j.seppur.2013.12.039http://doi.org/10.1016/j.seppur.2013.12.039

J. Ravi, T. Prathibha, K.A. Venkatesan et al., Third phase formation of neodymium (III) and nitric acid in unsymmetrical N,N-di-2-ethylhexyl-N′,N′- dioctyldiglycolamide. Sep. Purif. Technol. 85, 96-100 (2012). doi: 10.1016/j.seppur.2011.09.053http://doi.org/10.1016/j.seppur.2011.09.053

G.X. Sun, M. Liu, Y. Cui, et al. Synthesis of N,N′-dimethyl-N,N′-dioctyl-3- oxadiglycolamide and its extraction properties for lanthanides. Solvent Extr. Ion Exch. 28, 482-494 (2010). doi: 10.1080/07366299.2010.480932http://doi.org/10.1080/07366299.2010.480932

S. Yuji, T. Shoichi. Extraction of actinides(III), (IV), (V), (VI), and lanthanides(III) by structurally tailored diamides. Solvent Extr. Ion Exch. 20, 21-34 (2002). doi: 10.1081/SEI-100108822http://doi.org/10.1081/SEI-100108822

E.M. Nasab, Solvent extraction separation of uranium(VI)and thorium(IV) with neutral organophosphorus andamine ligands. Fuel. 116, 595-600 (2014). doi: 10.1016/j.fuel.2013.08.043http://doi.org/10.1016/j.fuel.2013.08.043

D. D. Dicholkar, P. Kumar, P. K. Heer et al., Synthesis of N,N,N′,N′-tetraoctyl-3- oxapentane-1,5-diamide (TODGA) and its steam thermolysis-nitrolysis as a nuclear waste solvent minimization method. Ind. Eng. Chem. Res. 52, 2457-2469 (2013). doi: 10.1021/ie302603qhttp://doi.org/10.1021/ie302603q

D. Magnusson, B. Christiansen, J.P. Glatz et al., Demonstration of a TODGA based extraction process for the partitioning of minor actinides from a PUREX raffinate. Solvent Extr. Ion. Exch. 27, 26-35 (2009). doi: 10.1080/07366290802544726http://doi.org/10.1080/07366290802544726

J. Ravi, K.A. Venkatesan, M.P. Antony et al., Tuning the diglycolamides for modifier-free minor actinide partitioning. J. Environ. Chem. Eng. 1, 690-695 (2013). doi: 10.1007/s10967-012-1905-9http://doi.org/10.1007/s10967-012-1905-9.

V. Chavan, V. Thekkethil, A.K. Pandey et al., Assembled diglycolamide for f-element ions sequestration at high acidity. React Polym. 74, 52-57(2014). doi: 10.1016/j.reactfunctpolym.2013.10.011http://doi.org/10.1016/j.reactfunctpolym.2013.10.011

E.A. Mowafy, D. Mohamed. Extraction behavior of trivalent lanthanides from nitric acid medium by selected structurally related diglycolamides as novel extractants. Sep. Purif. Technol. 128, 18-24 (2014). doi: 10.1016/j.seppur.2014.03.005http://doi.org/10.1016/j.seppur.2014.03.005

S.L. Gwang, U. Masahito, M. Kouji et al., Separation of major impurities Ce, Pr, Nd, Sm, Al, Ca, Fe, and Zn from La using bis(2-ethylhexyl)phosphoric acid (D2EHPA)-impregnated resin in a hydrochloric acid medium. Sep. Purif. Technol. 71, 186-191 (2010). doi: 10.1016/j.seppur.2009.11.020http://doi.org/10.1016/j.seppur.2009.11.020

Y. Cui, Y.Q. Wang, M.P. Pang et al., Effect of diluents on the extraction and separation of Fe(III) and Cu(II) from hydrochloric acid solutions using N,N,N′,N′-tetrabutyl succinamide. Hydrometallurgy. 152, 1-6 (2015). doi: 10.1016/j.hydromet.2014.11.012http://doi.org/10.1016/j.hydromet.2014.11.012

H.T. Chang, M. Li, Z.G. Liu, Y.H. Hu et al., Study on separation of rare earth elements in complex system. J. Rare Earths. 28, 116-119 (2010). doi: 10.1016/S1002-0721(10)60270-0http://doi.org/10.1016/S1002-0721(10)60270-0

F. Xie, T.A. Zhang, D. David et al., A critical review on solvent extraction of rare earths from aqueous solutions. Miner. Eng. 56, 10-28 (2014). doi: 10.1016/j.mineng.2013.10.021http://doi.org/10.1016/j.mineng.2013.10.021

S.S. Tong, X.W. Zhao, W.H. Zhou, Solvent extraction study of rare earth elements from chloride medium by mixtures of sec-nonylphenoxy acetic acid with Cyanex301 or Cyanex302. Hydrometallurgy. 100, 15-19(2009). doi: 10.1016/j.hydromet.2009.09.006http://doi.org/10.1016/j.hydromet.2009.09.006

S. Dutta, P.K. Mohapatra, V.K. Manchanda, Separation of 90Y from 90Sr by a solvent extraction method using N,N,N′,N′-tetraoctyl diglycolamide (TODGA) as the extractant. Appl. Radiat. Isot. 69, 158-162 (2011). doi: 10.1016/j.apradiso.2010.09.016http://doi.org/10.1016/j.apradiso.2010.09.016

Y. Cui, J.H. Yang, G. Yang et al. Effect of diluents on extraction behavior of rare earth elements with N,N,N′,N′-tetrabutyl-3-oxy-glutaramide from hydrochloric acid. Hydrometallurgy. 121-124, 16-21 (2012). doi: 10.1016/j.hydromet.2012.04.013http://doi.org/10.1016/j.hydromet.2012.04.013

G. Yang, D. Ma. Study of 3-oxa-glutaramide extractting rare earth metals from hydrochloric acid system. Thesis. University of Jinan. (2010).

P.N. Pathak, L.B. Kumbhare, V.K. Manchanda, Structural effects in N,N-dlalkyl amides on their extraction behavior toward uranium and thorium. Solvent Extr. Ion Exch. 19, 105-126 (2011). doi: 10.1081/SEI-100001377http://doi.org/10.1081/SEI-100001377

E. Hosten, H.E. Rohwer. Complexation reactions of uranyl with arsenazo III. Anal. Chim. Acta. 355, 95-100 (1997). doi: 10.1016/S0003-2670(97)81616-9http://doi.org/10.1016/S0003-2670(97)81616-9

S.P.K. Donald, H.K. Kean, C.Y.J. Chan, The application of the pitzer equations to 1-1 electrolytes in mixed solvents. Solut. Chem. 14, 635-651 (1985). doi: 10.1007/BF00646056http://doi.org/10.1007/BF00646056

S. Manohar, J. Ananthaswamy, G.J. Atkinson. Application of Pitzer equations for quaternary systems: sodium chloride-sodium nitrate-sodium acetate-water and potassium chloride-potassium nitrate-potassium acetate-water at 25.degree. C. Chem. Eng. Data. 37, 459-463 (1992). doi: 10.1021/je00008a019http://doi.org/10.1021/je00008a019

A. Shimada, T. Yaita, H. Narita, et al. Extraction studies of lanthanide(III) Ions with N,N′‐dimethyl‐N,N′‐diphenylpyridine‐2,6‐dicarboxyamide (DMDPhPDA) from nitric acid solutions. Solvent Extr. Ion Exch. 22, 147-161 (2004). doi: 10.1081/SEI-120030392http://doi.org/10.1081/SEI-120030392

M. Anitha, M.K. Kotekar, D.K. Singh et al., Solvent extraction studies on rare earths from chloride medium with organophosphorous extractant dinonyl phenyl phosphoric acid. Hydrometallurgy. 146, 128-132 (2014). doi: 10.1016/j.hydromet.2014.03.015http://doi.org/10.1016/j.hydromet.2014.03.015

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Effect of radiolysis of TODGA on the extraction of TODGA/n-dodecane toward Eu(III): An experimental and DFT study

Heavy ion-induced MCUs in 28 nm SRAM-based FPGAs: Upset proportions, classifications, and pattern shapes

Extraction of lanthanide ions with N,N,N′,N′-tetrabutyl-3-oxa-diglycolamide from nitric acid media

Th (IV) and U(VI) removal by TODGA in ionic liquids: Extraction behavior and mechanism, and radiation effect

Solvent extraction of U(VI) by N,N-dimethyl-N′,N′-dioctylsuccinylamide and N,N-dimethyl- N′,N′-didecylsuccinyl amide in cyclohexane

Related Author

No data

Related Institution

Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics

Beijing National Laboratory for Molecular Sciences, Radiochemistry and Radiation Chemistry Key Laboratory for Fundamental Science, College of Chemistry and Molecular Engineering, Peking University

Department of Radiochemistry, China Institute of Atomic Energy

State Key Laboratory of ASIC and System, Fudan University

School of Physics and Electronic Information Engineering, Jining Normal University

Address：Editorial Office of NST, 2019 Jialuo Road, Jiading, Shanghai 201800, China Postal code：201800
Email：nst@sinap.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 沪ICP备05005479号-1 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰