Kinetics study of the solvated electron decay in THF using laser-synchronised picosecond electron pulse

Vincent De Waele; Sébastien SORGUES; Pascal PERNOT; Jean-Louis MARIGNIER; Mehran MOSTAFAVI

doi:10.1016/S1001-8042(07)60010-4

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Kinetics study of the solvated electron decay in THF using laser-synchronised picosecond electron pulse

RADIOCHEMISTRY, RADIOPHARMACEUTICALS AND NUCLEAR MEDICINE | Updated：2021-01-29

- Kinetics study of the solvated electron decay in THF using laser-synchronised picosecond electron pulse
- Nuclear Science and Techniques Vol. 18, Issue 1, (2007)
- Affiliations：
  
  1.Laboratoire de Chimie Physique/ELYSE, UMR CNRS/UPS 8000, Bât. 349, Université Paris-Sud, 91405 Orsay, France
- Author bio：
  
  Corresponding author, e-mail:mehran.mostafavi@lcp.u-psud.fr
  
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- DOI：10.1016/S1001-8042(07)60010-4 CLC： O621.25
- Published：20 January 2007，
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Vincent De Waele, Sébastien SORGUES, Pascal PERNOT, et al. Kinetics study of the solvated electron decay in THF using laser-synchronised picosecond electron pulse. [J]. Nuclear Science and Techniques 18(1):10-15(2007)
DOI：

Vincent De Waele, Sébastien SORGUES, Pascal PERNOT, et al. Kinetics study of the solvated electron decay in THF using laser-synchronised picosecond electron pulse. [J]. Nuclear Science and Techniques 18(1):10-15(2007) DOI： 10.1016/S1001-8042(07)60010-4.

Kinetics study of the solvated electron decay in THF using laser-synchronised picosecond electron pulse 1 first-author 1 1 1 1 corresp Corresponding author, e-mail:mehran.mostafavi@lcp.u-psud.fr Corresponding author, e-mail:mehran.mostafavi@lcp.u-psud.fr mehran.mostafavi@lcp.u-psud.fr Laboratoire de Chimie Physique/ELYSE, UMR CNRS/UPS 8000, Bât. 349, Université Paris-Sud, 91405 Orsay, France Laboratoire de Chimie Physique/ELYSE, UMR CNRS/UPS 8000, Bât. 349, Université Paris-Sud, 91405 Orsay, France Picosecond pulse radiolysis of neat tetrahydrofuran (THF) shows a fast decay of the solvated electron within 2.5ns. The decay of the solvated electron observed at 790nm is because of spur reaction. A numerical simulation using time dependent Smoluchowski equation containing a sink term with a distance dependent reaction rate is used to fit the pulse-probe data and shows that the geminate reaction can proceed at long distance in this low polar solvent. Picosecond pulse radiolysis Neat tetrahydrofuran (THF) Laser triggered Picosecond electron accelerator References Bronskill M J , Taylor W B , Wolff R K , et al . Rev. Sci. Instrum . 1970 , 41 : 333 . Rev. Sci. Instrum Wolff R K , Bronskill M J , Aldrich J E , et al . J. W. J. Phys. Chem . 1973 , 77 : 1350 . J. W. J. Phys. Chem Hunt J W , Wolff R K , Bronskill M J , et al . J. Phys. Chem . 1973 , 77 : 425 . J. Phys. Chem Sumiyoshi T , Katayama M . Chem. Lett ., 1982 , 1887 . Chem. Lett Jonah C D , Hart E J , Matheson M S . J. Phys. Chem . 1973 , 77 : 1838 . J. Phys. Chem Jonah C D , Matheson M S , Miller J R , et al .. J. Phys.Chem . 1976 , 80 : 1267 . J. Phys.Chem Bartels D M , Cook A R , Mudaliar M , et al . J. Phys. Chem. A . 2000 , 104 : 1686 . J. Phys. Chem. A Muroya Y , Lin M , Wu G , et al . Radiat. Phys. Chem . 2005 , 72 , 169 . Radiat. Phys. Chem Buxton GV , Proc R. Soc. London A 1972, 328, 9. and Buxton G V in charged particles and photon interaction with matter ( Mozumder A , Hatano Y , Eds). Marcel Dekker, Inc. New York : 2004 , 331 . Proc R. Soc. London A 1972, 328, 9. and Buxton G V in charged particles and photon interaction with matter Laverne J A , Pimblott S M . J. Phys. Chem . 1991 , 95 , 3196 and J. Phys. Chem Pimblott S M , Laverne J A . J. Phys. Chem . 1992 , 96 , 8904 . J. Phys. Chem Pimblott S M , Laverne J A , Bartels D M. , et al . J. Phys. Chem . 1996 , 100 : 9412 . J. Phys. Chem De Waele V , Sorgue S , Pernot P , et al . Chem. Phys. Lett . 2006 , 423 , 30 . Chem. Phys. Lett Hong K M , Noolandi J . Chem. Phys . 1978 , 68 : 5163 , Chem. Phys Hong K M , J. Chem. Phys . 1978 , 69 : 5026 . J. Chem. Phys Sano H , Tachiya M . J. Chem. Phys ., 1979 , 71 : 1276 J. Chem. Phys Tachiya M . Radiat. Phys. Chem . 1987 , 30 : 75 . Radiat. Phys. Chem Wojcik M , Tachiya M , Tagawa S , et al . in Charged Particles and Photon interaction with matter Eds. A. Mozumder and Y. Hatano . Marcel Dekker, Inc. New York ( 2004 ) page 259 . Charged Particles and Photon interaction with matter Belloni J , Monard H , Gobert F , et al . Nucl. Instr. Meth ., 2005 , A539 : 527 . Nucl. Instr. Meth Kozawa T , Yoshida Y , Tgawa S . Jpn. Appl. Phys . 2002 , 41 : 4208 . Jpn. Appl. Phys Salmon G A , Seddon A , Fletcher W . Can. J. Chem . 1974 , 52 : 3259 . Can. J. Chem Green N J B , Pilling M J , Pimblott S M , et al . J. Phys. Chem ., 1990 , 94 : 251 . J. Phys. Chem Pimblott S M . J. Phys. Chem ., 1991 , 95 : 6946 . J. Phys. Chem Goulet T , Jay-Gerin J P . J. Chem. Phys ., 1992 , 96 : 5076 . J. Chem. Phys Soroushian B , Lampre I , Pernot P , et al .. Chem. Phys. Lett ., 2004 , 394 : 313 . Chem. Phys. Lett Martini I B , Barthel E R , Schartz B J . J. Phys. Chem ., 2000 , 113 : 11245 . J. Phys. Chem Murata S , Tachiya M . J. Chim. Phys ., 1996 , 58 : 1577 . J. Chim. Phys Krissinel E. B , Agmon N J . Comput.Chem . 1996 , 17 : 1085 . Comput.Chem Dodelet J P , Freeman G R . Can. J. Chem ., 1975 , 53 : 1265 . Can. J. Chem Renou F , Pernot P , Bonin J , et al . J. Phys. Chem., A 2003 , 107 : 6587 . J. Phys. Chem., A Burel L , Mostafavi M , Murata S , et al . J. Phys. Chem. A ., 1999 , 103 : 5888 . J. Phys. Chem. A 10.1016/S1001-8042(07)60010-4 O621.25 2007-01-20 2021-01-19 2007 Nuclear Science and Techniques 01 18

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