Separation of <sup>152+154</sup>Eu, <sup>90</sup>Sr from radioactive waste effluent using liquid-liquid extraction by polyglycerol phthalate

M.F. Attallah; S.E. Rizk; S.A. Shady

doi:10.1007/s41365-018-0423-z

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Separation of ^152+154Eu, ⁹⁰Sr from radioactive waste effluent using liquid-liquid extraction by polyglycerol phthalate

NUCLEAR CHEMISTRY, RADIOCHEMISTRY, NUCLEAR MEDICINE | Updated：2021-02-07

- Separation of ^152+154Eu, ⁹⁰Sr from radioactive waste effluent using liquid-liquid extraction by polyglycerol phthalate
- Nuclear Science and Techniques Vol. 29, Issue 6, Article number: 84(2018)
- Affiliations：
  
  1.Analytical Chemistry and Control Department, Hot Laboratories Center, Atomic Energy Authority of Egypt, 13759 Abu Zaabal, Cairo, Egypt
  2.Chemistry of Nuclear Fuel Department, Hot Laboratories Center, Atomic Energy Authority of Egypt, 13759 Abu Zaabal, Cairo, Egypt
  3.Technology of Nuclear Fuel Department, Hot Laboratories Center, Atomic Energy Authority of Egypt, 13759 Abu Zaabal, Cairo, Egypt
- Author bio：
  
  Corresponding author: E-mail: dr.m.f.attallah@gmail.com; Mohamed.attallah@eaea.org.eg M.F. Attallah.
- Funds：
- DOI：10.1007/s41365-018-0423-z
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M.F. Attallah, S.E. Rizk, S.A. Shady. Separation of ^152+154Eu, ⁹⁰Sr from radioactive waste effluent using liquid-liquid extraction by polyglycerol phthalate. [J]. Nuclear Science and Techniques 29(6):84(2018)
DOI：

M.F. Attallah, S.E. Rizk, S.A. Shady. Separation of ^152+154Eu, ⁹⁰Sr from radioactive waste effluent using liquid-liquid extraction by polyglycerol phthalate. [J]. Nuclear Science and Techniques 29(6):84(2018) DOI： 10.1007/s41365-018-0423-z.

摘要

Abstract

A new polyglycerol phthalate extractant was prepared and characterized using Fourier transform infrared (FTIR) spectroscopy, proton nuclear magnetic resonance (,1,H NMR) spectroscopy, and thermogravimetric analysis (TGA). A preliminary study of the extraction of long-lived (,90,Sr and ,152+154,Eu) and short-lived (,90,Y) radionuclides by polyglycerol phthalate was performed. The influence of different diluents, concentration of the acid, type of acid, and various interfering ions was explored. The stripping of ,152+154,Eu radionuclide was studied by using different acid solutions and it was found that sulfuric acid was the ideal acid for this purpose. Furthermore,152+154,Eu was extracted from the fission products (,90,Sr) and the extraction% of ,90,Sr was found to improve in the presence of interfering ions.

关键词

Keywords

Liquid-liquid extractionLong-lived radioisotopesPolyglycerol phthalateNuclear waste

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Separation of 152+154Eu, 90Sr from radioactive waste effluent using liquid-liquid extraction by polyglycerol phthalate

DOI：10.1007/s41365-018-0423-z

摘要

Abstract

关键词

Keywords

references

Separation of ^152+154Eu, ⁹⁰Sr from radioactive waste effluent using liquid-liquid extraction by polyglycerol phthalate