Radiation synthesis and characteristics of PTFE-g-PSSA ion exchange membrane applied in vanadium redox battery

Radiation synthesis and characteristics of PTFE- g -PSSA ion exchange membrane applied in vanadium redox battery 1 first-author 1 1 1 corresp Corresponding author, e-mail: mlzhai@pku.edu.cn Corresponding author, e-mail: mlzhai@pku.edu.cn mlzhai@pku.edu.cn 1 1 1 1 1 Beijing National Laboratory for Molecular Sciences, Department of Applied Chemistry, College of Chemistry & Molecular Engineering, Peking University, Beijing 100871, China Beijing National Laboratory for Molecular Sciences, Department of Applied Chemistry, College of Chemistry & Molecular Engineering, Peking University, Beijing 100871, China Radiation-induced grafting of styrene onto polytetrafluoroethylene (PTFE) membranes was studied by a simultaneous irradiation technique. Grafting was carried out using γ-radiation from a 60 Co source at room temperature. Effects of absorbed dose, atmosphere, dose rate, and the concentration of initial monomer on the degree of grafting ( DOG ) were investigated and the most appropriate grafting condition was obtained. Subsequently, sulphonation of the grafted PTFE membrane (PTFE- g -PS) was carried out and a series of ion exchange membranes (PTFE- g -PSSA) was prepared. Further characterizations of FTIR, TGA, and SEM testified that grafting and sulphonation of the membranes were successfully processed; moreover, grafting of styrene not only occurred in the surface of PTFE membrane, but also in the micropores of the membrane. Ion exchange capacity ( IEC ) and conductivity were found increase with the grafting yield. The results suggest that at a low dose, such as 17 kGy, the ion exchange membrane (IEM) which will be suitable for vanadium redox battery (VRB) use can be obtained. PTFE Radiation grafting Styrene Ion exchange membrane Vanadium redox battery References Sum E , Skyllas-Kazacos M . Journal of Power Sources , 1985 , 15 : 179 - 190 . Journal of Power Sources Mohammadi T , Skyllas-Kazacos M . Journal of Membrane Science , 1995 , 107 : 35 - 45 . Journal of Membrane Science Mohammadi T , Skyllas-Kazacos M . Journal of Appllied Electrochemistry , 1997 , 27 ( 2 ): 153 - 160 . Journal of Appllied Electrochemistry Nasef M M , Saidi H , Dessouki M A , et al . Polymer International , 2000 , 49 : 399 - 406 . Polymer International Hwang G J , Ohya H . Journal of membrane science . 1996 , 120 ( 1 ): 55 - 67 . Journal of membrane science 10.1016/S1001-8042(07)60018-9 O631.3 + 4,TM911 Supported by The Scientific Research Foundation of State's Education Ministry for the Returned Overseas Chinese Scholars. 2007-01-20 2021-01-19 2007 Nuclear Science and Techniques 01 18