Influences of ⁷Li Enrichment on Th-U Fuel Breeding for an Improved Molten Salt Fast Reactor (IMSFR)

Influences of 7 Li Enrichment on Th-U Fuel Breeding for an Improved Molten Salt Fast Reactor (IMSFR) 1 2 3 first-author 1 2 3 1 2 1 2 3 1 2 3 corresp chenjg@sinap.ac.cn. chenjg@sinap.ac.cn. chenjg@sinap.ac.cn 1 2 3 corresp xuhongjie@sinap.ac.cn. xuhongjie@sinap.ac.cn. xuhongjie@sinap.ac.cn. Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China CAS Innovative Academies in TMSR Energy System, Shanghai, China 201800 CAS Innovative Academies in TMSR Energy System, Shanghai, China 201800 University of Chinese Academy of Sciences, Beijing, China 100049 University of Chinese Academy of Sciences, Beijing, China 100049 The Molten salt fast reactor (MSFR) shows great promise with high breeding ratio (BR), large negative temperature coefficient of reactivity (TCR), high thermal-electric conversion efficiency, inherent safety, as well as on-line reprocessing. Based on an Improved MSFR (IMSFR) optimized by adding axial fertile salt and a graphite reflector, the influences of 7 Li enrichment on Th-U breeding are investigated, aiming to provide a feasible selection for the molten salts with high fissile breeding and a relatively low technology requirement for 7 Li concentration. With the self-developed molten salt reactor reprocessing sequence (MSR-RS) based on SCALE6.1, the burn-up calculations with on-line reprocessing are carried out. Parameters are explored including BR, 233 U production, double time (DT), spectrum, 6 Li inventory, and neutron absorption, as well as the tritium production. The results show that the 7 Li enrichment of 99.95% is appropriate in the fast fission reactor. In this case, BR above 1.10 can be achieved for a long time, corresponding to the 233 U production of 130 kg per year and DT of 36 years. After 80 years’ operation, the tritium production for 99.5% is only about 7 kg, and there is no obvious increase compared to that for 99.9995%. IMSFR 7 Li enrichment Thorium Fuel breeding 1 Introduction 1 Molten salt reactor (MSR), as the only liquid fuel reactor of the six candidate reactor types selected by the Generation-IV Forum (GIF), shows great promise with high thermal-electric conversion efficiency, inherent safety, as well as on-line reprocessing [ 1 1 , 2 2 ]. Furthermore, the high breeding ratio (BR) and negative temperature coefficient of reactivity (TCR) have been demonstrated theoretically in the pure fission Molten Salt Fast Reactor (MSFR), and the long-life radioactive nuclides is of low production based on the Th-U fuel cycle [ 3 3 , 4 4 ]. MSR originated from the Aircraft Reactor Experiment (ARE) [ 5 5 ], whose successful operating for 100 hours in 1954 certified the feasibility of MSR for the first time. Then the Molten-Salt Reactor Experiment (MSRE) [ 6 6 ], using FLiBe salt as the fuel carrier, was developed by the Oak Ridge National Laboratory (ORNL) and ran 4.5 years from 1965, which proved the safety and reliability of MSR. Afterwards, the Molten Salt Breeding Reactor (MSBR) [ 7 7 ] was proposed and studied by ORNL as well. The MSBR concept has an electrical power of 1 GWe, and the Th-U fuel breeding can be achieved even in a thermal spectrum, providing that an efficient reprocessing of fission products (FPs) and Pa was involved. Unfortunately, this program was ended in 1976. The MSBR concept was re-evaluated by the European Atomic Energy Community (Euratom). The results [ 8 8 ] show that the total TCR of MSBR is positive or slightly negative, and the complex reprocessing is a great challenge. Then, a no-graphite Molten Salt Fast Reactor (MSFR) [ 9 9 , 10 10 ] was proposed by the French National Academy of Sciences (CNRS). This MSFR concept is attractive for the characters with a large negative TCR, no graphite lifetime limitation, low waste production, and high Th-U breeding ratio (BR). Researches [ 3 3 , 11 11 ] on various fuels with different reprocessing efficiency in MSFR were carried out by D. Heuer et al . Findings include but are not limited to BR in equilibrium is 1.08 based on Th-U fuel cycle, and the corresponding production of 233 U is 95 kg per year, while the double time (DT) of 233 U is 56 years. The results also show that the reprocessing period declines from 4 m 3 /d for MSBR to 40 L/d, because of the low neutron absorption cross-section of FPs in fast spectrum. Currently, the utilization of thorium with molten salt attracts lots of attention all over the world in both the fission and the fusion fields. For the pure fission reactors, besides the MSBR and MSFR, other reactors including AHTR in USA [ 12 12 ], FUJI series in Japan [ 13 13 , 14 14 ], MOSART in Russia [ 15 15 ], also give the concept design with different targets. In 2011, the Strategic Project “Future Advanced Nuclear Energy–Thorium-based Molten Salt Reactor System (TMSR)” was launched by the Chinese Academy of Sciences (CAS), aiming to solve the key technical issues of TMSR and realizing the efficient utilization of Thorium [ 16 16 ]. For the fusion reactors, the molten salt blanket is used for high neutron wall loads and high efficient power conversion [ 17 17 ]. Researches show that the addition of fissile isotopes in the molten salt, such as Flibe + Weapon Grade (WG) PuF 4 or Spent Fuel Grade (SFG) PuF 4 , could improve the neutronic performance and the energy multiplication in ARIES-ST [ 17 17 ]. In the improved fusion concept PACER, the molten salts of Flibe (92 mol%) mixed with ThF 4 and WG-PuF 4 were investigated [ 18 18 ]. The results show that tritium self-sufficiency is provided if the RG-PuF 4 is higher than 0.75 mol% and the 233 U production is about 2870 kg/year because of the existence of thorium in the molten salt and the large flux of neutrons with high energy produced by fusion. In the Laser Inertial Confinement Fusion-Fission Energy (LIFE) Engine, the neutronic performance is also investigated with the molten salt mixed with 233 U [ 19 19 ]. The results show that the tritium breeding ratio (TBR), the energy multiplication, and the fissile fuel breeding all increase with the increase of 233 U in the molten salt. The influences of 6 Li enrichment are studied as well, which indicates that the TBR increases while the fissile production decreases with the increase of the 6 Li enrichment. Studies on the Th-U fuel cycle have been carried out in our group. They are mainly focused on the fission reactors, such as the analysis of Th-U fuel breeding in a graphite-moderated MSR [ 20 20 ] and in a ZrH-moderated MSR [ 21 21 ]. In the re-evaluation of MSFR, we found that the neutron absorption of alloy in the axial direction of the active core is so high that a considerable number of neutrons are wasted, and the utilization efficiency of the fertile salt is somewhat too low. So the geometry of MSFR was improved by adding fertile salt on the axis direction of the active core to improve the Th-U fuel breeding and by adding a graphite reflector for fertile saving [ 22 22 ]. Another problem is that the enrichment of 7 Li used in the molten salt of MSFR is 99.995%, which brings a great challenge to the purification technology. Even if it could be realized based on the present technology, the economic cost is too high. In this paper, the influences of 7 Li enrichment are analyzed based on the pure fission Improved MSFR (IMSFR), aiming to give an appropriate reference both suitable for high BR and low technological requirement. Sect. 2 gives the general description of IMSFR and the calculation tools. Then, the results of the burn-up calculations with on-line reprocessing are presented in Sect. 3. The influences of 7 Li enrichment are discussed from the aspects of BR, 233 U production and DT, spectrum, 6 Li inventory, and neutron absorption, as well as tritium production. Finally, the conclusions are given in Sect. 4. 2 General Description of IMSFR and Calculation Tools 1 2.1 General Description of IMSFR 2 The standard model of IMSFR is a pure fission fast reactor with a thermal power of 3000 MWth and a mean fuel temperature of 1023 K, which takes reference to the MSFR [ 3 3 ]. The cross and vertical sections of IMSFR are shown in Fig. 1 Fig. 1 , following with the main parameters in Table 1 Table 1 . There are mainly two partitions in the IMSFR, namely the fuel zone and the fertile zone, corresponding to the fuel salt and the fertile salt. The composition of the fuel salt is set as 22.5(HM)F 4 -77.5LiF in mol%. For the Th-U fuel cycle, HM stands for the heavy metal initially composed of 232 Th and 233 U, and the ratio of 232 Th and 233 U is adjusted for the reactor criticality. The composition of the fertile salt is also 22.5(HM)F 4 -77.5LiF in mol%, where the initial HM is only 232 Th. The proportion of (HM)F 4 is fixed at 22.5 mole% because of the low eutectic point of 838 K. The adopted enrichment of 7 Li in the MSFR is 99.995%, which will be further studied in this paper. 1 1 Parameters 1 1 Value 1 1 Thermal power (MWth) 1 1 3000 1 1 Composition of fuel salt (mol%) 1 1 77.5LiF-20ThF 4 -2.5 233 UF 4 1 1 Composition of fertile salt (mol%) 1 1 77.5LiF-22.5ThF 4 1 1 Temperature of fuel salt (K) 1 1 1023 1 1 Temperature of fertile salt (K) 1 1 973 1 1 Volume of fuel salt (m 3 ) 1 1 18 1 1 Volume of fertile salt (m 3 ) 1 1 8.45 1 1 Initial inventory of 233 U (t) 1 1 4.80 1 1 Initial inventory of 232 Th (t) 1 1 58.70 (fuel: 38.27+fertile: 20.43) 1 1 Density of molten salt at 1023 K (g ⋅ cm -3 ) 1 1 4.10 1 1 Dilatation coefficient (g ⋅ cm -3 ⋅ K -1 ) 1 1 -8.82×10 -4 1 1 Density of graphite (g ⋅ cm -3 ) 1 1 2.30 1 1 Density of alloy (g ⋅ cm -3 ) 1 1 8.86 1 1 Density of B 4 C (g ⋅ cm -3 ) 1 1 2.52 1 1 Enrichment of 10 B (%) 1 1 18.4 1 1 Diameter of the core (cm) 1 1 225.5 1 1 Height of the core (cm) 1 1 225.5 1 1 Reprocessing period of gas and insoluble heavy metal/s 1 1 30 1 1 Reprocessing period of fuel salt (d) 1 1 450 1 1 Reprocessing period of fertile salt (d) 1 1 210 The fuel zone (red area shown in Fig. 1 Fig. 1 ) consists of the active core and the external fuel circuit (including collectors, salt-bubble separators, heat exchangers, pumps, and pipes). The active core is a compact cylinder (height/diameter =1) with a diameter of 225.5 cm. The liquid fuel salt flows through the core from the bottom to the top and then to the heat exchangers with 16 groups of pumps outside. At the same time, the heat produced by fission is taken out of the active core to the heat exchangers then to the secondary loop. The total volume of the fuel salt is 18 m 3 , half of which is in the active core and the other half in the external circuit. The fertile salt surrounds the active core in both the radius direction and the axial direction with a thickness of 30 cm (blue area shown in Fig. 1 Fig. 1 ). The fuel salt and the fertile salt are separated by the Ni-based alloy with a thickness of 2 cm. The activation products of the alloy have been studied in a fluoride salt-cooled high-temperature reactor (FHR) [ 23 23 ], but further study is still needed in the IMSFR to confirm its stability and security. Surrounding the fertile salt is the graphite reflector (yellow area in Fig. 1 Fig. 1 ), which is adopted to the fertile saving [ 22 22 ]. Between the external circuit of the fuel salt and the graphite reflector, B 4 C of 10 cm (green area in Fig. 1 Fig. 1 ) is arranged to stop the neutrons leaking out of the reactor. The most external surface is also Ni-based alloy which serves as the structure material. Continuous boundary conditions are adopted between the material of the fuel salt, the alloy, the fertile salt, graphite, and B 4 C, while vacuum boundary condition is used outside the most layer out of the alloy. 2.2 Calculation tools: SCALE6.1 and MSR-RS 2 SCALE6.1 [ 24 24 ] is a comprehensive code package developed and maintained by ORNL, which can be used for criticality safety, burn-up calculation, radiation shielding, radioactive source term analysis, sensitivity and uncertainty analysis, and so on. In this paper, the module of CSAS (Criticality Safety Analysis) is used for the criticality calculation, the TRITON (Transport Rigor Implemented with Time-dependent Operation for Neutronic depletion) module performs for the problem-dependent cross-section processing and multi-group neutron transport calculation, and the ORIGEN-S (Oak Ridge Isotope Generation Code System) module serves for the depletion and decay calculations. The KMART6 (Keno Module for Activity- Reaction Rate Tabulation) module is used for the reaction rate of relevant nuclides. Other modules are also invoked, such as CENTRM/PMC and BONAMI which process the cross sections in the resolved and unresolved resonance energy regions, respectively. For MSR, the on-line reprocessing is an outstanding feature compared to the traditional solid fuel reactors. The extraction of FPs brings great advantages on the neutron economy and the Th-U fuel breeding. In addition, 233 U and 232 Th can be refueled on line for the reactor criticality, which is beneficial to decrease the excess reactivity and the inventory of fissile. However, tools at hand, such as MCNPX and SCALE, are not sufficient to simulate the complex reprocessing, especially for the functions of refueling and extracting with changing rates versus time. So the module of MSR-RS based on SCALE6.1 was developed particularly for the burn-up simulation of MSR in our previous work [ 25 25 , 26 26 ]. The flow chart of MSR-RS is shown in Fig. 2 Fig. 2 . First, the geometry and the molten salts are initialized for the input files. Second, the neutron transportation and depletion are calculated by TRITON and ORIGEN-S. Meanwhile, FPs are removed and 233 Pa is extracted as well to decay into 233 U out of the core. In addition, 233 U and 232 Th are injected into the fuel salt in order to maintain the reactor criticality and keep the inventory of HN constant. The cycle calculation is performed iteratively until the depletion time reaches the value set by the user. A 238-group cross-section database is selected in this paper, and 388 nuclides are tracked in the trace quantities. In every step of the depletion calculations, about 1600 nuclides are tracked including fissions and decays. For the nuclide i , the burn-up equation is shown in Eq. (1): <math display="block" id="M1"><mrow><mtable columnalign="left"><mtr columnalign="left"><mtd columnalign="left"><mrow><mfrac><mrow><mtext>d</mtext><msub><mi>N</mi><mi>i</mi></msub></mrow><mrow><mtext>dt</mtext></mrow></mfrac><mo>=</mo><mstyle displaystyle="true"><munderover><mo>∑</mo><mrow><mi>j</mi><mo>=</mo><mn>1</mn></mrow><mi>m</mi></munderover></mstyle><msub><mi>l</mi><mrow><mi>i</mi><mi>j</mi></mrow></msub><msub><mi>λ</mi><mi>j</mi></msub><msub><mi>N</mi><mi>j</mi></msub></mrow></mtd><mtd columnalign="left"><mrow><mo>+</mo><mover accent="true"><mi>ϕ</mi><mo>¯</mo></mover><mstyle displaystyle="true"><munderover><mo>∑</mo><mrow><mi>j</mi><mo>=</mo><mn>1</mn></mrow><mi>m</mi></munderover></mstyle><msub><mi>f</mi><mrow><mi>i</mi><mi>j</mi></mrow></msub><msub><mi>σ</mi><mi>j</mi></msub><msub><mi>N</mi><mi>j</mi></msub><mo>−</mo><mo stretchy="false">(</mo><msub><mi>λ</mi><mi>i</mi></msub><mo>+</mo><mover accent="true"><mi>ϕ</mi><mo>¯</mo></mover><msub><mi>σ</mi><mi>i</mi></msub><mo stretchy="false">)</mo><msub><mi>N</mi><mi>i</mi></msub></mrow></mtd></mtr><mtr columnalign="left"><mtd columnalign="left"><mrow/></mtd><mtd columnalign="left"><mrow><mo>−</mo><msubsup><mi>λ</mi><mi>i</mi><mi>r</mi></msubsup><msub><mi>N</mi><mi>i</mi></msub><mo>+</mo><msub><mi>B</mi><mi>i</mi></msub><mtext> </mtext><mi>i</mi><mo>=</mo><mo stretchy="false">(</mo><mtext>1,2,...,</mtext><mi>m</mi><mo stretchy="false">)</mo><mn>.</mn></mrow></mtd></mtr><mtr columnalign="left"><mtd columnalign="left"><mrow/></mtd><mtd columnalign="left"><mrow/></mtd></mtr></mtable></mrow></math> in which, N i is the atom density of nuclide i , λ i is the decay constant, σ i is the one group absorption cross section, <math id="M2"><mover accent="true"><mi>ϕ</mi><mo>¯</mo></mover></math> is the average neutron flux, l ij is the branch ratio to i when j decays, and f ij is the branch ratio to i after j absorbs a nuetron. The last two parameters <math id="M3"><mrow><msubsup><mi>λ</mi><mi>i</mi><mi>r</mi></msubsup><msub><mi>N</mi><mi>i</mi></msub></mrow></math> and B i stand for the rates of extracting and refueling, respectively. And <math id="M4"><mrow><msubsup><mi>λ</mi><mi>i</mi><mi>r</mi></msubsup><mo>=</mo><mo>∈</mo><mo>/</mo><msub><mi>T</mi><mi>r</mi></msub></mrow></math> is the parameter similar to the decay constant. ϵ stands for the efficiency of reprocessing, and T r is the period of reprocessing. In this paper, the extraction of FPs and the refueling of 233 U and 232 Th are realized by changing these reprocessing parameters in ORIGEN-S. The on-line reprocessing includes the refueling of HN and the extracting of FPs. The extracting system involves two key processes [ 3 3 ]. One is the mechanical extraction of gaseous FPs and non-dissolved metals via an on-line He gas bubbling system. The other is the chemical removal of lanthanides and other soluble FPs via batch reprocessing by the on-site facilities. The He gas bubbling system can remove the gaseous FPs and the non-dissolved metals rapidly, so the remove period is set as 30 s. The chemical reprocessing is relatively slow and is set as 40 L/d. The fuel salt and the fertile salt are 18 m 3 and 8.45 m 3 , respectively, so their reprocessing periods are 450 d and 210 d. Meanwhile, 233 Pa and 233 U in the fertile salt are also extracted along with the molten salt reprocessing, aiming to reduce its neutron absorption and improve the Th-U conversion capability. Because of the on-line refueling which makes it possible for MSR with low excess reactivity, the effective multiplication factor ( K eff ) is set at 1.005±0.005 during all the operating time. 3 Results and discussion 1 Burn-up calculations are carried out with MSR-RS based on the IMSFR, and the influences of 7 Li enrichment from 98% to 99.9995% are explored. The BR, DT, and 233 U production are demonstrated in Sect. 3.1 and 3.2, and reasons are explored from the aspects of spectrum, 6 Li inventory, and neutron absorption in Sect. 3.3 and 3.4. Finally, the tritium production is analyzed in Sect. 3.5. 3.1 Th-U Breeding Ratio 2 BR is defined by the product rate over the disappearance rate of fissile, or the capture rate of fertile over the absorption rate of fissile. For Th-U fuel cycle, it can be expressed as [ 20 20 ]: <math display="block" id="M5"><mrow><mi>B</mi><mi>R</mi><mo>=</mo><mfrac><mrow><msubsup><mi>R</mi><mtext>c</mtext><mrow><msup><mrow/><mrow><mtext>232</mtext></mrow></msup><mtext>Th</mtext></mrow></msubsup><mo>+</mo><msubsup><mi>R</mi><mtext>c</mtext><mrow><msup><mrow/><mrow><mtext>234</mtext></mrow></msup><mtext>U</mtext></mrow></msubsup><mo>−</mo><msubsup><mi>R</mi><mtext>c</mtext><mrow><msup><mrow/><mrow><mtext>233</mtext></mrow></msup><mtext>Pa</mtext></mrow></msubsup></mrow><mrow><msubsup><mi>R</mi><mtext>a</mtext><mrow><msup><mrow/><mrow><mtext>233</mtext></mrow></msup><mtext>U</mtext></mrow></msubsup><mo>+</mo><msubsup><mi>R</mi><mtext>a</mtext><mrow><msup><mrow/><mrow><mtext>235</mtext></mrow></msup><mtext>U</mtext></mrow></msubsup></mrow></mfrac><mn>,</mn></mrow></math> in which R a and R c stand for the neutron capture rate and the absorption rate, respectively. The results are shown in Fig. 3 Fig. 3 . From the chart we can see that, when the enrichment of 7 Li is 99.995%, BR is approximately at 1.11 in equilibrium based on the improved geometry. It is obviously promoted when compared to that in the reference MSFR [ 3 3 ], which results from the contribution of the fertile salt in the axial direction. As also can be seen from the chart, when the enrichment is above 99.95%, BR’s evolution with time keeps nearly the same. But when the enrichment is 98%, BR declines drastically to less than 1.0 because of the neutron absorption of 6 Li. Then, 6 Li is consumed (more detailed discussion is shown in Sect. 3.4) and its neutron absorption decreases as the evolution of the reactor, leads to an increase of BR. After about 50 years’ evolution, BR, with a different enrichment of 7 Li, tends to be the same. We also notice that BR declines rapidly at the early time, and it is because of the accumulation of FPs. In short, according to the evolution of BR, the enrichment of 7 Li could be set at the range between 99.5% and 99.95% rather than 99.995%. 3.2 233 U Production and DT 2 When BR is bigger than 1.0, the fissile produced is more than that consumed. For the IMSFR with on-line reprocessing, the extracted 233 Pa from the fertile salt decays to 233 U in half a year. The 233 U extracted from the core and that decayed from 233 Pa are partially refueled into the active core for criticality, and the remaining (if any is left) is the net 233 U production, which is defined as: <math display="block" id="M6"><mrow><mi>M</mi><mo>=</mo><msubsup><mi>M</mi><mrow><mtext>ex</mtext></mrow><mrow><msup><mrow/><mrow><mtext>233</mtext></mrow></msup><mtext>U</mtext></mrow></msubsup><mo>+</mo><msubsup><mi>M</mi><mrow><mtext>ex</mtext></mrow><mrow><msup><mrow/><mrow><mtext>233</mtext></mrow></msup><mtext>Pa</mtext></mrow></msubsup><mo>−</mo><msubsup><mi>M</mi><mrow><mtext>re</mtext></mrow><mrow><msup><mrow/><mrow><mtext>233</mtext></mrow></msup><mtext>U</mtext></mrow></msubsup><mn>,</mn></mrow></math> where ex and re stand for extracting and refueling, respectively. For more clarity, the relative 233 U production (M r ) is used in this paper. It is obtained by dividing the net 233 U production to the initial inventory of 233 U (M 0 ), which is expressed as: <math display="block" id="M7"><mrow><msub><mi>M</mi><mi>r</mi></msub><mo>=</mo><mfrac><mrow><msubsup><mi>M</mi><mrow><mtext>ex</mtext></mrow><mrow><msup><mrow/><mrow><mtext>233</mtext></mrow></msup><mtext>U</mtext></mrow></msubsup><mo>+</mo><msubsup><mi>M</mi><mrow><mtext>ex</mtext></mrow><mrow><msup><mrow/><mrow><mtext>233</mtext></mrow></msup><mtext>Pa</mtext></mrow></msubsup><mo>−</mo><msubsup><mi>M</mi><mrow><mtext>re</mtext></mrow><mrow><msup><mrow/><mrow><mtext>233</mtext></mrow></msup><mtext>U</mtext></mrow></msubsup></mrow><mrow><msub><mi>M</mi><mn>0</mn></msub></mrow></mfrac><mn>.</mn></mrow></math> That is to say, when M r reaches 1.0, the net production of 233 U equals that of M 0 (4.8 t), which means the fissile doubles and it is sufficient to start a new IMSFR. The corresponding time is DT. Hence, the 233 U production per year can be derived as the following equation: <math display="block" id="M8"><mrow><mi>m</mi><mo>=</mo><msub><mi>M</mi><mn>0</mn></msub><mo>/</mo><mi>D</mi><mi>T</mi><mn>.</mn></mrow></math> Fig.4 Fig.4 presents M r versus time, while Fig. 5 Fig. 5 exhibits DT and the 233 U production per year with the different 7 Li enrichment. As shown in the two figures, when the enrichment of 7 Li is 99.995%, the production rate of 233 U promotes from 95 kg/year in the reference MSFR [ 3 3 ] to 130 kg/year in the IMSFR, while DT shortens from 56 years to 36 years. The advantages of the IMSFR are certified again from the aspects of 233 U production and DT. As also can be seen from Fig. 4 Fig. 4 , when the enrichment is above 99.95%, the 233 U production in different cases is nearly the same. There is no obvious improvement on Th-U fuel breeding when the enrichment is 99.9995% compared to that for 99.95%, and this is the same with DT and the 233 U production rate as show in Fig. 5 Fig. 5 . When the enrichment is 99.5%, the 233 U production declines and the DT extends to more than 40 years. For the case of 98%, the net 233 U production even could not reach the initial inventory in 80 years. In short, taking into account the 233 U production and DT, the 7 Li enrichment should be set at the range between 99.5% and 99.95%. 99.95% is recommended in the IMSFR because it is suitable for both Th-U fuel breeding and a relatively low technical requirement on 7 Li purification. 3.3 Spectrum 2 In this section, the normalized lethargy spectral are explored to understand the influences of 7 Li enrichment on Th-U fuel breeding more deeply. Figure 6(a) Figure 6(a) and Fig. 6(b) Fig. 6(b) give the spectra at the initial time with a series of 7 Li enrichment for the fuel salt and fertile salt, respectively. As can be seen from Fig. 6(a) Fig. 6(a) , there is no obvious distinction in the fuel salt with different 7 Li enrichment. However, when it comes to the fertile salt, significant differences appear, as shown in Fig. 6(b) Fig. 6(b) . The lower the 7 Li enrichment is, the harder the spectrum is. The reason is that the neutrons generated in the active core are moderated during the travelling from the fuel salt to the fertile salt, and the neutron absorption cross section of 6 Li is much bigger in the low-energy region than in the high-energy region. Therefore, when there is plenty of 6 Li in the fertile salt, the low-energy neutrons are absorbed, leading to the decline of the spectrum in the low-energy region. The little deviation of spectra in the fuel salt is also because of the absorption of 6 Li. When the 7 Li enrichment is higher than 99.95%, there is not enough 6 Li, so the spectrum keeps nearly the same as the case of 99.9995%. In other words, the 7 Li enrichment of 99.95% is recommended as well from the aspect of spectrum. Then, in the second part of this section, the spectral’s evolution with time is studied in the case that the 7 Li enrichment is 99.95%. The results are exhibited in Fig. 6(c) Fig. 6(c) and Fig. 6(d) Fig. 6(d) , which are also corresponding to the fuel salt and the fertile salt. From the chart we can see that the spectra in both the fuel salt and the fertile salt have almost no change from the startup to the 60th year. Only a little deviation appears which mainly results from the large neutron absorption cross-section of FPs, such as Xe and Sm. In a word, the enrichment of 7 Li has a more important influence on spectrum in the fertile salt than that in the fuel salt, which is because the neutron absorption cross section of 6 Li in the low-energy region is larger than that in the high-energy region. 3.4 Inventory of 6 Li and Neutron Absorption 2 Further researches are carried out by analyzing the inventory of 6 Li and the neutron absorption of the main nuclides, including 6 Li, 232 Th, and 233 U. Fig. 7 Fig. 7 gives the evolution of 6 Li with different enrichments of 7 Li. As can be seen from the chart, when the enrichment of 7 Li is higher than 99.95%, the inventory of 6 Li in the core is less than 5 g, which is so little that it has almost no effect on the thermal neutrons. However, when the enrichment of 7 Li is 99.5% or less, the mass of 6 Li is more than 20 g, which significantly affects the neutron absorption as well as the Th-U fuel breeding. The relative neutron absorption of the main nuclides versus the enrichment of 7 Li is given in Fig. 8 Fig. 8 at the startup time and at the 36th year (DT is 36 years when the enrichment of 7 Li is 99.95%). The solid line stands for the neutron absorption at startup. Information can be obtained from the chart that the neutron absorption of 6 Li declines as the increasing of the 7 Li enrichment due to the decline of 6 Li’s inventory. Meanwhile, the absorption of 232 Th increases while the absorption of 233 U keeps nearly the same. So according to Eq. (2), BR increases and then tends to equilibrium with the increasing of 7 Li enrichment. That is to say, when the enrichment of 7 Li is 99.5% or lower, the neutron absorption of 6 Li is so high that a certain number of neutrons are wasted, which leads to the reduction of 232 Th’s neutron capture. When the enrichment is higher than 99.95%, the neutron absorption of 6 Li is relatively low, and it has little influence on 232 Th’s neutron capture. The dashed line in Fig. 8 Fig. 8 represents the absorption at the 36th year. As shown in the chart, the neutron absorption of 6 Li, 232 Th, and 233 U change a little with the variation of the 7 Li enrichment. That is because after 36 years’ burn-up, 6 Li is consumed to a very low level, which has been shown in Fig. 7 Fig. 7 . Then, the neutron absorption at startup and at the 36th year are compared in Fig. 8 Fig. 8 . When the enrichment of 7 Li is 99.95%, the neutron absorption of 232 Th and 233 U is slightly lower at the 36th year than that at startup. That’s because of the accumulation of FPs, which absorbs a certain amount of neutrons in the core. Fortunately, with the on-line reprocessing, the influence of FPs has decreased to a very low level. 3.5 Tritium Production 2 In the MSRE, it is found that the tritium is mainly from the irradiation of 6 Li [ 27 27 ], and the generation reaction is as follows: <math display="block" id="M9"><mrow><mi>n</mi><msup><mo>+</mo><mn>6</mn></msup><mtext>Li</mtext><msup><mo>→</mo><mn>3</mn></msup><mtext>H</mtext><msup><mo>+</mo><mn>4</mn></msup><mtext>He</mtext><mn>.</mn></mrow></math> In the IMSFR with LiF molten salt, the decrease of 7 Li enrichment would inevitably lead to the increase of 6 Li inventory and the production of tritium. For the fusion reators, the production of tritium is useful to the D-T fussion reaction, so the increase of 6 Li in the Flibe or LiF molten salts contributes to the TBR and the tritium self-sufficiency [ 19 19 ]. However, the IMSFR concept is a pure fission fast reactor but not a fusion one. The tritium is extracted as the He gas bubbling because it is undisolved in the molten salt, and following work is needed to collect it. So it is undesired for the possibility of releasing to the atmosphere [ 28 28 ] and should be as little as possible in the fission reactor. In this subsection, the production of tritium is investigated finally. As shown in Fig. 9 Fig. 9 , after 80 years’ operation, the tritium production is about 7 kg when the enrichment of 7 Li is 99.95%, and it is nearly the same to the case of 99.9995%. But when the enrichment of 7 Li is 99.5%, the production of tritium is more than 11 kg. And it even reaches to nearly 30 kg in the 80th year when the enrichment of 7 Li is 98%. So when the 7 Li enrichment of 99.5% is still recommended from the aspect of tritium production. 4 Summary 1 In this paper, the influences of 7 Li enrichment on BR, 233 U production, DT, spectrum, 6 Li inventory, neutron absorption, and tritium production are analyzed by MSR-RS based on the IMSFR. Conclusions can be reached that: • There is no obvious improvement on Th-U fuel breeding when the enrichment of 7 Li is 99.9995% compared to that for 99.95% in the molten salt fast reactor. There is also no obvious increase on the tritium production when the 7 Li enrichment is 99.95% compared to that for 99.9995%. • When the enrichment of 7 Li is lower than 99.5%, the Th-U breeding is influenced obviously, mainly because of the high neutron absorption of 6 Li, which leads to the decline of 232 Th’s neutron capture. • The 7 Li enrichment of 99.95% is appreciated and recommended for the IMSFR. 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(Science Press), Shanghai Institute of Applied Physics, the Chinese Academy of Sciences, ChineseNuclear Society and Springer Nature Singapore Pte Ltd. 2017 This is a post-peer-review, pre-copyedit version of an article published in Nuclear Science and Techniques. The final authenticated version is available online at: http://dx.doi.org/10.1007/s41365-017-0250-7 http://dx.doi.org/10.1007/s41365-017-0250-7 . 2017 Nuclear Science and Techniques 07 28