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EXTRACTION OF AMERICIUM AND LIGHT RARE EARTHS BY 2-ETHYL HEXYL PHOSPHONIC ACID 2-ETHYL HEXYL ESTER

EXTRACTION OF AMERICIUM AND LIGHT RARE EARTHS BY 2-ETHYL HEXYL PHOSPHONIC ACID 2-ETHYL HEXYL ESTER

Zhu Yongjun
Jiao Rongzhou
Nuclear Science and TechniquesVol.6, No.3pp.140-145Published in print 01 Aug 1995
24500

The extraction behavior of trace Am (Ⅲ) and Eu (Ⅲ) from nitrate medium with HEHEHP in kerosene was studied. LgD/pH and lgD/ [H2A2] dependence plots are given. Calculated values of lgKex for Eu, Nd and Am are-0.13±0.08, -1.36±0.10, -1.89 ±0.18, respectively. Extraction equilibrium equations were deduced under proper conditions. Calculated values of DAm and DRE are in accordance with experimental ones.

Americium/rare earths separationHEHEHP extractionNumerical solution
References
1 Claiborne H C. Neutron-induced transmutation of high-level radioactive waste. ORNL-TM-3694, Tenn(USA): Oak Ridge Ntional Lab, 1972: 86
2 Bush R P, Mills A L. The fourth international conference on nuclear fuel reprocessing and waste management. RECOD'94 Proceedings, 24-28 April 1994. London, Held by British Nuclear Industry Forum
3 Bond W D, Leuze R E. Feasibility studies of partitioning of commercial high-level wastes generated in spent nuclear fuel reprocessing. ORNL-5012, Tenn(USA): Oak Ridge Ntional Lab, 1975: 111
4 Xu G X, Yuan C Y. Solvent extraction of rare earths (in Chinese). Beijing: Science Press, 1991: 141-150, 401-417
5 Li Z H, Jiao R Z, Zhu Y J. Chinese J Nucl Sci Eng, 1994; 14(1): 64-71