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254/185 nm photolysis of p-nitrophenol

LOW ENERGY ACCELERATORS AND RADIATION APPLICATIONS

254/185 nm photolysis of p-nitrophenol

ZHAO Sufang
MA Hongjuan
WANG Min
CAO Changqing
XIONG Jie
XU Yunshu
YAO Side
Nuclear Science and TechniquesVol.21, No.3pp.141-145Published in print 20 Jun 2010
43900

Degradation of low-concentration p-nitrophenol (p-NP) aqueous solution was carried out in 254/185 nm photolysis. The effects of Mn2+, pH value, O2 and O3 on the degradation efficiency have been investigated. It was observed that the singlet oxygen scavenger Mn2+ did not affect the degradation of p-NP. In acidic and alkaline solutions, the degradation efficiency was enhanced in comparison to that in neutral solution. The presence of O2 dramatically promoted the degradation of p-NP, while that of O3 impeded it.

VUVp-NitrophenolDegradationAdvanced oxidation process
References
[1] Ye J, Singh A, Ward O P. World J Microbiol Biotechnol, 2004, 20(2), 117-135.
[2] Einschlag F S G, Felice J I, Triszcz J M. Photochem Photobiol Sci, 2009, 8: 953-960.
[3] Gonzalez M G, Oliveros E, Wörner M, et al. J Photochem Photobiol C, 2004, 5(3): 225-246.
[4] ZHAO Sufang, MA Hongjuan, WANG Min, et al. Photochem. Photobiol. Sci., 2010, 9: 710-715
[5] Battino R, Rettich T R, Tominaga T. J Phys Chem Ref Data, 1983, 12: 163-178.
[6] Buxton G. V, Greenstock C L, Helman W P, et al. J Phys Chem Ref Data, 1988, 17(2): 513-886.
[7] Du Y, Zhou M, Lei L. J Hazard Mater, 2007, 139(1): 108-115.
[8] Sun Y, Pignatello J J. Environ. Sci. Technol., 1993, 27(2): 304-310.
[9] Utset B, Garcia J, Casado J, et al, Chemosphere, 2000, 41(8), 1187-1192.
[10] Kunai A, Hata S, Ito S, et al. J Am Chem Soc, 1986, 108(19), 6012-6016.
[11] Tunde A, Dombi A, J Photochem. Photobiol A, 2007, 188(2-3): 409-418.
[12] Ma H J, Wang M, Pu C Y, et al. J Hazard Mater, 2009, 165(1-3): 867-873.
[13] Ma H J, Zhao S, Zhang J, et al. J Photochem. Photobiol A, 2009, 202(1): 67-73.
[14] Quici N, Litter M I, Braun A A, et al. J Photochem. Photobiol A, 2008, 197(2-3): 306-312.
[15] O'Neill P, Steenken S, van der Linde H, et al. Radiat Phys Chem, 1978, 12(1-2): 13-17.
[16] Beltran F J, Gomez-Serrano V V, Duran A. Water Res, 1992, 26: 9-17.