Introduction
In petroleum exploration and development, a chemical source is commonly used for nuclear well logging. This technique employs Cs137 or AmBe sources to assess the formation properties [1, 2]. However, concerns persist regarding the environmental pollution risks posed by chemical sources during transportation and measurement. Consequently, pulsed neutron well logging, noted for its safety and controllability, has emerged as a viable alternative to traditional well logging.
Pulsed neutron logging is indispensable for evaluating complex oil and gas reservoirs. It relies on a pulsed neutron generator, which is an electronically controlled small-accelerator neutron source. By adjusting the pulse emission frequency, it can achieve integrated measurements [3] of multiple formation parameters, such as density, porosity, lithology [4]. Although pulsed neutron logging reduces radioactive risks and provides richer formation information than traditional well logging through a single measurement, the strong penetration capability of high-energy neutrons and the variable distribution of secondary gamma rays may have a mutual influence on gamma or neutron detection [5-8], especially in LWD measurements, where particles may penetrate through mud pipes and reach the detectors. Consequently, there may be a higher level of tool-related information included in the detector-recorded information, thereby reducing the proportion of formation responses. To reduce non-formation-related information, tool shielding must be studied. To understand the rationale behind shielding design, requires the review of the principles of pulsed neutron logging.
Overview of pulsed neutron well logging principle
In pulsed neutron logging, taking a D-T source as an example, after the emission of 14 MeV fast neutrons, the initial energy loss of the neutrons occurs mostly because of inelastic collisions [9]. During neutron deceleration, multiple inelastic collisions may occur, resulting in inelastic scattering rays with characteristic energies specific to different elements. As fast neutrons decelerate to thermal neutrons and are absorbed by target nuclei in geological formations, characteristic energy-capturing gamma-rays are emitted. The elemental composition of geological formations can be determined by analyzing the energy spectra of these two types of gamma rays [10].
Simultaneously, as the neutron energy decreases, elastic collisions gradually become dominant during neutron deceleration. During elastic collisions, the neutron energy is transferred to the target nucleus in a manner consistent with the conservation of kinetic energy within the system, as shown in Eq. 1.
Motivation for investigating boron shielding
When designing pulsed-neutron tools, several types of detectors must be incorporated to enable various measurement modes within a single tool. LWD tools differ from cable tools because of the inclusion of a mud pipe, which can lead to thermal neutron leakage and the subsequent generation of captured gamma-rays when the tool elements capture these neutrons. To illustrate the effect of the described physical processes on downhole detection, as shown in Fig. 1, we considered a pulsed neutron tool comprising one neutron detector and one gamma-ray detector with a mud pipe. Figure 1 outlines the potential physical pathways that particles reaching the detectors might traverse, as indicated by paths ①–⑦. For neutrons, the possible paths include ①–④. Gamma is summarized as paths ⑤–⑦.
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Path ① and Path ③: After the 14 MeV neutrons are generated, they are moderated through the tool, borehole, and formation, forming thermal neutrons in the formation and subsequently in the tool. Path ②: After the 14MeV neutrons are generated from the source, they are moderated through the tool, borehole, and formation, after which the thermal neutrons formed are captured by the neutron detector. Path ④: Fast neutrons generated from the source may be directly moderated within the tool (including the mud pipe) and ultimately detected using neutron detectors. Path ⑤: Following path ①, the neutrons returning to the tool generate captured and inelastic gamma rays. Path ⑥: This is Similar to Path ⑤, but the generation of captured and inelastic gamma-rays occurs within the formation. Path ⑦:The neutrons that follow path ④ generate both captured and inelastic gamma rays inside the tool.
For Path ④, neutrons might be detected directly without interacting with the formation, which is disadvantageous for measuring formation porosity. In gamma paths ⑤ and ⑦, gamma rays generated within the tool (including the mud pipe) need to be shielded, especially for common tool elements like Fe, Ni, and Mn, as tool-related contributions could lead to inaccuracies in determining the formation’s elemental content [11-13]. This issue arises because the tool’s spectrum may overshadow formation data, resulting in inaccuracies or incomplete subtraction of the tool’s spectrum, thereby complicating elemental measurement. Therefore, one feasible approach in spectrum analysis is to reduce the contribution of tool body elemental composition [14-16]. However, once fast neutrons emitted from the tool enter the formation, inelastic gamma-ray generation is inevitable, and these inelastic gamma rays produced by the tool cannot be eliminated through shielding [17]. Thus, for elemental measurement, it is crucial to shield the potential thermal neutrons that may undergo neutron capture reactions with the tool, such as by implementing shielding around the tool or mud pipe to prevent direct interactions of thermal neutrons with tool elements.
Boron is an important element inneutron shielding as it has a high thermal neutron absorption cross-section [18, 19]. Compared to other elements commonly used for neutron shielding, such as cadmium and gadolinium, boron releases relatively low gamma energy during the capture process, which can be removed by lower energy truncation. These characteristics render boron an effective shielding material. Previous studies [20-28] have demonstrated the feasibility of using Monte Carlo simulation software for tool design. These studies indicate that there are various materials available for thermal neutron shielding [29], including some novel materials [30-33], which exhibit both gamma and neutron shielding properties and are used in applications such as ionizing radiation shielding and medical diagnostics. Additionally, materials like boron concrete, borated polyethylene [34], and boron-containing stainless steel are employed in fields such as laboratory shielding [35] and nuclear power plant shielding [36]. However, high temperature and pressure in the downhole environment, along with tool volumetric constraints, pose new challenges for more effective shielding.
The primary challenge in well-logging tool shielding involves two key considerations. First, the spatial limitations of the tool restrict the use of thick shielding layers to block high-energy neutrons, requiring materials with high shielding efficiency to achieve maximum effectiveness within a compact space. Second, selecting appropriate shielding materials necessitates evaluating factors such as melting point, tensile strength, and hardness, allowing for a broader range of materials that can withstand high temperatures and complex structural demands within the tool.
This study investigates the design of boron-containing shielding for an LWD pulsed neutron tool, focusing on its impact on neutron and gamma detection. Monte Carlo simulations were used to examine various shielding materials and thicknesses around the neutron detector, assessing their effects on neutron count rates and ratios. Additionally, the internal and external shielding of the gamma detector was evaluated to determine its influence on gamma energy spectra and count rates. The aim of this study is to provide a reference framework for designing shielding in pulsed-neutron logging tools.
Pulsed neutron tool design
Monte Carlo modeling of the tool
The open-source Monte Carlo simulation software Geant4 (Geometry and Tracking 4) was used for evaluation [37]. This study employed a pulsed neutron logging tool currently under development. This tool can acquire critical formation parameters, such as elemental composition, density, and porosity. For integrated detection, both gamma and neutron detectors were included. To simulate pulsed neutron tool detection, the source was defined as a 14 MeV pulsed neutron source in Geant4. The detailed model is shown in Fig. 2.
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To differentiate the origins of the particles detected, the data processing in Geant4 is illustrated in Fig. 2. During particle transport, the type of particle produced is identified by calling the SteppingAction, such as gamma rays produced by neutron inelastic collisions or capture reactions. Subsequently, based on GetVertexPosition(), the position, called logicalVolume, where the gamma was generated is determined, such as formations, boreholes, tools, or mud pipes. If the particle reaches the detector, it is logged into HistoManager, enabling subsequent result output.
Neutron detector shields
The tool incorporates an internal mud pipe, primarily for transporting drilling mud during logging. After fast neutrons are emitted, thermal neutrons may travel directly to the neutron detectors via the mud pipe. To shield against these neutrons, neutron shielding is typically installed at the bottom of the neutron detectors within the tool, as shown in Fig. 2. The neutron detector was enveloped by three layers: the bottom layer was a neutron shield; the middle layer contained the detectors within an aluminum alloy detector room; and the top layer was an aluminum alloy detector shell.
To prepare boron compounds suitable for engineering applications, they must be processed into solid forms. However, boron compounds are inherently brittle and exhibit low solubility in steel, making the preparation of high-boron steel challenging as boron content increases. Therefore, to select the optimal shield material, three materials were evaluated for their impact on neutron measurements.
• Aluminum Boron Carbide (Al-B4C) With a density of 2.6 g/cm3, this composite material contains 40% B4C and 60% aluminum. It has a hardness range of 300–400 GPa and a melting point range of 190–200 ℃ [38].
• Boron Carbide (B4C) B4C is known for its high structural strength, this material has a density of 2.52 g/cm3 with a composition of B10 (76.9%) and C (23.1%). It exhibits a high hardness of 500 GPa and a melting point of 2350 ℃ [39, 40].
• Aluminum-Boron Alloy (Al-B) Al-B alloys are renowned for their high strength, excellent corrosion resistance. Selected material [41, 42] with a density of 2.45 g/cm3, including B10 (11%), Si (0.3%), Fe (0.35%), Ti (0.08%), K (1%), Na (0.5%), and Al (86.77%). Its hardness is in the range of 100–200 GPa with a tensile strength of 220–250 MPa and a melting point between 690–700 ℃.
Shields of gamma detector
In this tool, a far-gamma detector was used for density measurements, whereas a near-gamma detector was used for elemental measurements. The near-gamma detector consists of two shields: one shields against thermal neutrons migrating from the mud pipe, and the other shields against thermal neutrons migrating from outside the tool, as shown in Fig. 2.
Due to challenges in shaping pure boron and its high cost, this study used HNBR rubber mixed with boron for the external shielding of the tool. Given the structural constraints, the maximum thickness of the internal shielding was limited to 1.1 mm, thus a pure boron material was selected for internal shielding. Subsequent sections will focus on optimizing the shielding for the near-gamma detector and investigating the effects of different thicknesses and boron contents in both the internal and external shields on spectral elemental measurements.
Results analysis and discussion
This section presents a shielding design study based on the tool described above. To investigate the influence patterns of neutron and gamma detection in the tool, detector responses were obtained by altering the boron material and its thickness. A population of 108 particles was simulated. The tool was positioned centrally in the sandstone formation.
Shield design of neutron detector
Neutron spatial distribution analysis
This section first analyzes the distribution of thermal and fast neutrons inside the mud pipe. In Geant4, the X-Z cross-section of the mud pipe was extracted for flux analysis, as shown in Fig. 3a.
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The source-to-detector distances for the two neutron detectors are 28.8 cm and 69.2 cm, respectively. As shown in Fig. 3b, the number of low-energy neutrons (<1 MeV) decreases sharply as the source-to-detector distance increases. In Fig. 3c, the distribution of fast neutrons is primarily concentrated around the source. After emission, these fast neutrons are quickly moderated by the surrounding media, resulting in minimal distribution within the mud pipe, tool, and borehole, making it difficult for them to reach the near and far neutron detectors. In contrast, thermal neutrons, as shown in Fig. 3d, exhibit a distribution within the mud pipe that differs significantly from that of fast neutrons. Near the neutron detector, the number of thermal neutrons originating from the mud pipe decreases by approximately 9.7 times. Without adequate shielding, near-neutron detectors are significantly affected. In contrast, the far-source neutron detector is less affected, as the thermal neutrons inside the mud pipe are insulated from the external environment, allowing for different shielding designs for detectors at varying source-to-detector distances.
Material comparison
This section analyzes the performance of the three shielding materials, B4C, Al-B4C, and Al-B alloy, focusing on the near neutron count rate, near epithermal neutron count rate, far neutron count rate, and neutron ratio (the ratio of the near detector count rate to the far detector count rate) under different porosities, as shown in Fig. 4. For neutron porosity measurements, the detection sensitivity S is defined as Eq. 2.
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This phenomenon occurs because, with low-boron-content shielding, the detector receives an overwhelming amount of non-formation information, making it less sensitive to changes in formation porosity. The recommended materials in this study remain B4C and Al-B4C. Based on the trend in near-detector count changes with porosity, B4C provides the best shielding performance, while Al-B4C is a viable alternative to B4C.
The effect of shielding thickness
With B4C identified as the optimal shielding material, its effectiveness was evaluated at various thicknesses to observe changes in the neutron detector count rate. Figure 4 compares near and far neutron detectors at different shielding thicknesses. Changes in the shielding thickness of one detector did not affect the count pattern of the other. For detectors at two source distances, as porosity increases, the capacity of the formation to moderate neutrons is enhanced, resulting in a shorter moderation length and, consequently, fewer neutrons returning to the detectors. Consequently, the overall count rate decreases. Neutrons transmitted through the mud pipe remain unaffected by the surrounding environment; therefore, their counts stay constant. For the near-neutron detector, as shown in Fig. 4a, changing the shielding thickness results in a noticeable reduction in the count rate. In the far-neutron detector, shown in Fig. 4b, the differences gradually diminish with increasing porosity and tend to converge. This convergence occurs because, as formation information decreases, the proportion of nonformation information increases, potentially preventing the distant detector from accurately identifying formation information at high porosities.
Sensitivity variations in the near and far detectors for different thicknesses are shown in Fig. 4e. It can be observed that the thicker the shielding, the lower the sensitivity. For example, at a porosity of 25 p.u., the sensitivities of the near detector with shielding thicknesses of 0.1 mm and 6.25 mm are 1.58 and 1.67, respectively, indicating a 5.6% increase in sensitivity response. Figure 4f illustrates the count rate variations for both detectors at different shielding thicknesses. It is notable that the count rate for the far detector gradually stabilizes at a shielding thickness of 4 mm, with the neutron contribution mainly from the tool background and formation. In contrast, the count rate for the near-neutron detector stabilizes at a thickness of 5 mm. Therefore, for optimal neutron shielding design, a 5 mm thickness was selected for the near-neutron detector, and a 4 mm thickness for the far-neutron detector.
Shield design of gamma detector
Gamma spatial distribution analysis
To design an optimal gamma shield, it is essential to understand the distribution of gamma rays. Inelastic gamma rays are generated by high-energy neutrons through inelastic collisions, while captured gamma rays are produced by the capture of thermal neutrons. Thus, after neutrons pass through the mud pipe and tool, gamma information unrelated to the formation is generated. Figures 5a and b show the distribution of captured and inelastic gamma rays generated within the mud pipe, while Figs. 5c and d illustrate the distribution of captured and inelastic gamma rays generated within the tool.
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The source-to-detector distances for the gamma detectors were 45.1 cm and 87.8 cm, respectively. Within the mud pipe, as shown in Figs. 5a and b, the distribution of captured gamma rays is broader, whereas the inelastic gamma rays are primarily concentrated near the source. Additionally, as indicated in Fig. 3d, few captured gamma rays originate from the mud pipe. This is because the likelihood of hydrogen within the mud pipe undergoing capture reactions is lower than that of metal within the tool. However, as shown in Figs. 5c and d, a significant number of both captured and inelastic gamma rays are generated inside the tool. For the capture gamma flux, the attenuation at the near gamma detector is approximately 11.4 times that at the source, while the inelastic gamma rays decrease by a factor of 165. The attenuation of captured gamma rays is therefore less pronounced than that of inelastic gamma rays. Consequently, it is necessary to block the thermal neutrons passing through the mud pipe and reacting with the tool to reduce tool-related captured gamma contributions.
The effect of boron content
To evaluate the impact of boron shielding on gamma detection, this section examines variations in gamma count rates and energy spectra across shields with boron contents ranging from 0.1% to 99.9%. The thicknesses of the external and internal shielding were set to 10 mm and 1 mm, respectively. Figure 6 illustrates the proportional contributions of captured and inelastic gamma rays originating from the formation, tool, mud pipe, and borehole. The gamma contribution from the tool constitutes a significant portion and, therefore, needs to be reduced with an effective shield design. Due to the different physical mechanisms involved in generating inelastic versus captured gamma rays, the count rate of inelastic gamma rays remains relatively stable. However, for captured gamma rays, as boron content increases, the proportional contribution from the formation gradually rises, while the contribution from the tool decreases. For internal shielding, once the boron content reaches 75%, further increases do not significantly impact the count rate, as shown in Fig. 6a. At this level, the total count response from the formation increases by 2.93%, making a boron content of 75% the optimal choice for internal shielding material.
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Additionally, adjusting boron content in the external shield can achieve more effective shielding, as shown in Fig. 6b. When the external boron content reaches 25%, further increases no longer significantly enhance the shielding effect, with the formation’s contribution increasing by 9.56%.
The effect of shielding thickness
Figures 6c and d illustrate the changes in the proportional contributions of captured gamma rays from the formation, tool, mud pipe, and borehole as the thickness of the shielding increases. However, within the internal shielding, the increase in thickness did not significantly enhance the contribution of the formation to the capture of gamma rays, as shown in Fig. 6c, especially compared to the impact of boron content, as demonstrated in Fig. 6a. Therefore, for this shielding application, employing a method such as spraying boron powder could be a viable alternative to fabricating a geometric shield.
Figure 6d shows that the changes in the gamma contributions of the external shielding increase as the thickness varies from 5.2 mm to 14.2 mm. As the thickness of the external shielding increases, the proportion contributed by the mud pipe decreases approximately proportionally, whereas the proportion from the formation increases linearly.
The different trends in internal and external shielding are due to the fact that internal shielding primarily prevents thermal neutrons from the mud pipe from entering the tool, and the contribution of thermal neutrons from the mud pipe remains constant. Therefore, complete shielding of the mud pipe can be achieved at a certain level of shielding. In contrast, external shielding prevents thermal neutrons from entering the tool, and there are generally more thermal neutrons from the formation than from the mud pipe. Consequently, the shielding performance improves with increased thickness. This indicates that, for external shielding, a thicker setup is generally more beneficial. Within the constraints of the tool size, a maximum thickness of 14.2 mm was chosen, at which point the contribution from the formation increased by 5.18%.
Analysis on the gamma spectra
Figures 7a and b illustrate the near-gamma detector’s X-Y plane distribution and the spectra received by the near-gamma detector. There was significant diffusion of thermal neutrons into the interior of the tool from the outside and the mud pipe, leading to neutron capture by the tool’s elements and thereby generating interference. With the addition of boron to both the external and internal shielding, a noticeable reduction in the diffusion of thermal neutrons was observed, resulting in a lower neutron distribution inside the tool. The increased number of thermal neutrons in both external and internal shielding indicates an enhanced absorption effect of boron.
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The tool was made of stainless steel and contained high amounts of Fe and Ni. Therefore, without thermal neutron shielding, the gamma spectrum of the tool contained distinct peaks for Fe and Ni. The Fe peaks are located at 7.1 MeV and 7.6 MeV, while the Ni peak is at 6.6 MeV. In the captured gamma distribution transmitted through the mud pipe, contributions from iron and nickel can also be observed. In terms of count rate contributions, the order is tool > formation > mud pipe > borehole. Therefore, when the contributions from these four sections are combined, the information from the formation may be overshadowed by the tool information, making it difficult to analyze the formation elements. However, in the gamma spectrum, after implementing the shielding design, the contributions from both the tool and mud pipe were significantly reduced, demonstrating the effectiveness of the shielding.
Conclusion
This study investigated a boron-containing shielding design for a newly developed pulsed neutron-logging tool. The findings revealed that the impact of the mud pipe on the detector is significant and cannot be ignored. After fast neutrons are emitted, they slow down quickly due to the water in the mud pipe, resulting in the accumulation of a considerable amount of thermal neutrons. Since thermal neutrons in mud pipes do not provide formation information, both neutron and gamma detectors are significantly affected; therefore, an advanced shielding strategy is necessary.
First, for neutron detectors, simulations show that shielding materials with higher boron content, such as boron carbide, can achieve improved shielding effects. Considering the tool’s volumetric constraints, the distribution of neutrons, and the performance of the shielding thickness, the selected shielding thicknesses for the near- and far-neutron detectors were 5 mm and 4 mm, respectively. From the thickness comparison, at a porosity of 25 p.u., the near-neutron sensitivity shows a 5.6% increase in response.
Second, for the near-gamma detector, shielding thermal neutrons is equally important to prevent the tool-related capture of gamma rays produced when thermal neutrons enter the tool. Both internal and external shields were designed. Due to volumetric constraints, it is difficult to adjust the internal shield thickness, necessitating the use of a high-concentration boron powder coating with a boron content of 75%. Moreover, the thickness of the external shield can be increased, allowing for greater flexibility in design. The simulation shows that the optimal thickness is 14.2 mm with 25% boron content to minimize the tool effect. This manuscript provides references and insights into the neutron and gamma shielding design of pulsed neutron tools.
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