Thermodynamic oxygen isotope factors for uranium oxides have been calculated by means of the modified increment method. The sequence of 18O-enrichment in the uranium oxides with respect to the common rock-forming minerals is predicted as follows: spinel < uraninite ≤ brannerite ≤ hematite < rutile < pitchblende < cassiterite ≤ uranium blacks ≤ coffinite < sedovite ≤ UO3 < illite. Two sets of self-consistent fractionation factors between the uranium oxides and water and between the uranium oxides and the other minerals have been obtained for 0~ 1200°C. The theoretical results are applicable to the isotopic geothermometry of uranium ores when pairing with other gangue minerals in hydrothermal uranium deposits.
Vol.6, No.4
Select issueYearIssue
1995
4
Research article 01 Nov 1995
Zheng Yongfei
keyword:Oxygen isotopes;Fractionations;Theoretical calculations;Uranium oxides;Geothermometry;
Research article 01 Nov 1995
T. V. Prevenslik
The standard model of sonoluminescence suggests that the Coulomb barrier to deuterium fusion may be overcome by high bubble gas temperatures caused by compression heating if the bubble diameter remains spherical during bubble collapse. However, in the more likely collapse geometry of a pancake shape, the temperature rise in the bubbles is negligible. But the collapsing pancake bubble is found to significantly increase the frequency of the infrared energy available in the vibrational state of the water molecules at ambient temperature. For a collapse to liquid density, ultraviolet radiation at about 10 eV is found. Although the ultraviolet radiation is of a low intensity, higher intensities may be possible if the bubble collapse is enhanced by visible and infrared lasers. Neither hot nor cold fusion is predicted in bubble collapse, but the ultraviolet energy at about 10 eV developed in the bubble is sufficient to provide the basis for a new field of chemistry called ultrasound induced and laser enhanced cold fusion chemistry.
keyword:Cold fusion;Ultrasound;Ultraviolet;Theory;
Research article 01 Nov 1995
K. P. Ng,K. N. Yu,E.C.M. Young
A compartment model is employed to calculate the radionuclide concentrations in the ocean currents for a nuclear accient scenario where the long-lived 137Cs is totally discharged into the sea. The radionuclide concentrations in both the waters of Daya Bay and the adjacent South China Sea are considered. Using the concentration factors for the marine organisms: fish, crustacea and mollusca, their radionuclide concentrations are also estimated. In this way, the whole body radiation doses received by an individual due to ingestion of marine organisms from the Daya Bay and the South China Sea are calculated.
keyword:Marine foodchain;Nuclear power plant;137Cs;Whole body radiation dose;Ingestion;Hong Kong;
Research article 01 Nov 1995
Li Xiaolin,Zhu Jieqing,Gu Yingmei,Wu Xiankang,Tong Chunhan,Wang Yunliang,Shuai Dequan,Zhang Chengjiang
A combination of NAA and micro-PIXE was used to study concentrations and distributions of platinum group elements (PGE) in ores from Xinjie Cu-Pt deposit. The NAA results of the bulk indicate that the ores belong to the enriched Pt-Pd type. The element concentration maps of scanning micro-PIXE for the ores show that the occurence form of Pt is independent arsenide minerals. No PGE were detected in chalcopyrite of Xinjie Cu-Pt deposit. These information are economically beneficial to the mineral smelting process.
keyword:Platinum group elements;Neutron activation analysis;Scanning proton microprobe;China;
Research article 01 Nov 1995
吴 小华,夏 元复,H. M. Widatallah,沈 俭一,关 冰,陈 懿
The reduction process of Eu2O3 on TiO2 and other supports is investigated in detail by Mössbauer spectroscopy. The reducibility of Eu2O3 is greatly enhanced when it is supported on a surface of support. This is due to the solid-solid interaction between the oxide and the support.
keyword:Mössbauer spectroscopy;Eu2O3;Reducibility;Supports;Solid-solid interaction;Catalysis;Surface science;Hyperfine structure study;
Research article 01 Nov 1995
Yang Weifan,Zhao Zhizheng,Li Zongwei,Mu Wantong
Radioactivities of 189W are produced through an 192Os(n,α)189W reaction. Gamma ray spectroscopy from chemically separated tungsten sources using HPGe detector has revealed the presence of 22 gamma rays assigned to the decay of 189W. Of them, 18 gamma rays are new ones unreported until now.
keyword:Gamma-rays spectra;Chemical separation;Decay curve resolution;
Research article 01 Nov 1995
Zong Hongshi,Feng Sze-Shiang,Wang Zixing
Some useful relations in SU(N) algebra are given in this paper. These relations may be useful in deriving the many-body interaction in QCD.
keyword:SU(N) algebra;Many body interaction;Quantum chromodynamics;Hermitian operators;Many-dimensional calculations;
Research article 01 Nov 1995
Chen Jiansheng,Du Guoping,Zheng Zheng,Sun Jing
Infiltration and localization of preferential infiltration zones at the dam abutment are measured using radioactive tracer tests of flow in boreholes, meanwhile interconnection between boreholes and the energing water points is analysed. The theory and practice of radioactive tracer synthetic detective method are described to give methods and calculation formulae used under the condition of stable flow in single well to measure permeability coefficient and hydrostatic heads. Major single hole techniques including measurement for seepage line, velocity, rate of seepage flow and relationship of recharge of groundwater in aquifers are introduced briefly. The possibilities offered by natural tracers are analysed, including electric-conduct, pH-value and temperature of water as well as stable isotopes (D, 18O) and tritium. Furthermore, the sensibilities of this theory and methods were confirmed by detecting seepage flow field of Xinanjiang Dam.
keyword:Isotope tracers;Natural tracers;Single hole techniques;Seepage flow field;Hydrostatic heads;
Research article 01 Nov 1995
Cao Guoxian,Li Weiyi,Zhang Rongjun,Yu Huixin
Solid phase exchange radioiodination method was used to label the compound. Pharmacokinetics was studied in rats and the data were dealt with by computer. The results indicate that the compound would be a potential myocardial imaging agent.
keyword:Bivalent analog of practolol;Radioiodination;Pharmacokinetics;Myocardial imaging agent;125I;
Research article 01 Nov 1995
Luo Shunzhong,Qiao Jian,Pu Manfei,Liu Zhonglin,Zhao Pengji,Fu Yibei
Adsorption of a promising bone tumor therapeutic agent 153Sm-EDTMP (ethylene diamine tetramethylene phosphonic acid) and effects of several coexisting substances on adsorption and desorption were investigated using HA (hydroxyapatite) as an in vitro model. The adsorption is quantitative up to total deposition of 40 µmol/g HA, while nonquantitative when the complex concentration is above 40 µmol/g HA in the medium of pH=7.0±0.2. The uptake increases significantly with the Ca ions added. Desorption of the adsorped complexes is in the sequence of EDTMP»DTPA > EDTA. Two modes of adsorption of 153Sm-EDTMP on HA are suggested, the first one (≤ 40µmol/g HA) quantitatively covers the available surface and the second, by which, is less efficient, additional complexes are adsorped. Non-quantitative adsorption is attributed to Coulomb repulsion while the complex concentration ranging from 40 to 80 µmol/g HA.
keyword:153Sm-EDTMP;Bone tumor therapeutic agent;Hydroxyapatite;Adsorption and desorption;Adsorption modes;
Research article 01 Nov 1995
Zhang Hongyuan,Wang Lanjin,Cai Ping,Fan Zhengping,Wen Quanfa
The chromosome and chromatid type aberration can be induced by benzene and the dicentric and ring ones were not observed in vitro experiment but observed in vivo one. In vitro experiment a good linear regression can be given between benzene concentrations and total aberration cells while power regression for radiation dose. The chromosome aberrations induced by benzene combined with radiation in rabbit blood lymphocytes are higher than in bone marrow cells.
keyword:Gamma-radiation;Benzene;Combined-effect;Chromosome aberration;
Research article 01 Nov 1995
Shao Songsheng,Feng Jialin,Xu Rong
The peripheral blood lymphocyte chromosomes in a case of 60Co γ rays accident were examined at 2.5 h after exposure. The frequency of the dicentrics plus centric rings was 89% and exposure dose was estimated to be 4.78 (4.53〜4.88) Gy. The examinations of lymphocyte chromosome aberration within follow-up 12 a showed that the incidence of Dic+R reduced with lg regression (r =-0.9895). While the number of cells with stable aberration remained unchanged and showed a tendency to increase. During the period of leukemia, bone marrow cell chromosome aberrations were studied by method of G-banding. Of 13 cells observed, 4 cells belonged to normal karyotypes. Among 9 aberration cells, 12 aberrations were detected. The majority of which were classified as translocation, deletion and inversion. Numeric aberrations were -9, -12, -20, -22, -y. This case suggested that acute lymphocytic leukemia was induced after radiation accident.
keyword:Chromosome aberration;Exposure accident;Acute lymphocytic leukemia;60Co;