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Vol.4, No.4
Research article 01 Nov 1993
冯 松林,钟 溟,任 闽秦,刘 年庆,朱 节清,杨 长义,P. Larsson,K. Malmqvist,王 禹,韩 其勇
The nodular cast iron samples were prepared with the normal nodularizing process, in which the important antinodularizing elements Pb, Bi and Al were added respectively in order to research the influence of them on the nodularization of the graphites. The nodular graphites were extracted from the nodular cast iron by the electrolytic technique. The distribution of trace elements in nodular and deformed graphite were measured by Scanning Proton Microprobe (SPM). Most of the adding elements Pb, Bi and Al existed in matrix as impurities, a part of them intruded into the nodular graphites. A new suggestion of Ti antinodularizing properties had been proposed. The influence of Pb, Bi and Al on the nodularization was indirectly performed through Ti. Therefore, Ti is one of the most important antinodularizing elements.
keywordNodular graphite;Antinodularizing element;Elemental distribution SPM;
Research article 01 Nov 1993
Xu Bujin,Zhang Yongxi
A study on the behavior of p, p'-DDT in flooded soil was conducted from 1990 to 1991. 14C-p,p'-DDT was used as a tracer. TLC, ARG techniques were used. A chromatography scanner was used to determine the radioactivity in spots of TLC plates. The behavior of DDT in flooded soil is different from that in upland soil. The dissipation of DDT was faster, DDT and its metabolites moved down faster, and more radioactivity became to bound residue in flooded soil as compared with those in upland situation. In extracts, DDT, DDD, DDE, DDA and an unidentified product were detected and their amounts were changed with time. About 90 % of the DDT disappeared and DDD became the key component of extractable residue within 8 weeks in flooded soil, whereas DDT took about 80% of the methanol extractable residue in 43 rd week sample of upland soil.
keywordDDT;Dissipation;Distribution;Metabolites;
Research article 01 Nov 1993
Yang Ruiying,Yuan Chao
Cenozoic basalts in the eastern part of Liaoning-Jilin contain abundant mantle-derived inclusions. The rock types of the ultramafic inclusions are composed mostly of spinel lherzolite and a few websterites. In order to study the origin of inclusions, the concnetrations of several trace elements have been measured in samples by NAA. According to geochemical characteristics of trace elements, there are two types of spinel lherzolite inclusions. The first type is refractory residues left after partial melting of the upper mantle and the second type is metasomatizing refractory residues. The websterites inclusions formed by segregation of basaltic melt derived from high degree of melting of mantle source rocks.
keywordUltramafic inclusion;Primitive mantle;Residual mantle;Partial melting;Mantle metasomatism;Spinel lherzolite;Websterite;
Research article 01 Nov 1993
Dai Zhongning,Ren Chigang,Liu Nianqing
A program for quantitative PIXE analysis of thick sample (TSPIXE) without reference material has been developed at Fudan University. Our program can be applied to the energy range of 10 keV to 10 MeV and is suitable for the analysis of all elements with 11 < Z < 92. NBS reference materials were analyzed to provide the experimental test of TSPIXE program.
keywordThick sample;PIXE analysis;TSPIXE;
Research article 01 Nov 1993
Wang Cailin,Wang Bo,Li Shiqing,Wang Shaojie,Yao Ning
Positron lifetimes in polyethylene glycol (PEG) polymer have been measured as a function of polymerization degree N (N = 25-500). It is observed that all the positron parameters are strongly dependent on N when N ≤ 250, and then tend to constant levels when N ≥ 250. The variations of the longest-lived component (I3, τ3) show that the size of free-volume holes has a minimum at N = 100 and the hole concentration deereases with N. These trends may be due to the variations in crystallinity, the chain ends, entanglements and the Van der Waals interaction between segments. The variations of the second component (I2, τ2) with N reflect the changes of defect properties in crystalline regions of PEG.
keywordPotitron annihilation;Polyethylene glycol;Free-volume hole;Defect;
Research article 01 Nov 1993
Zheng Sixiao
The properties and designment of the strong focusing lens system and the application to metal modification of gear cutting tools are described. The focused ion beam produced by a special three asymmetric voltage lens has the unique features of short midfocal length, strong focusing and omitted focusing electric power. These properties of strong focusing lens system are due to the application of the high energy ratio of 20 to 50 onto the lens.
keywordStrong focussing lens;Focussed ion beam Metal;Modification;
Research article 01 Nov 1993
Hu Ya'er,Yi Ningyu,He Luming,Xia Zongqin
A technique for studying in vivo the production rate and turnover rate constant of mouse brain M-receptors was established. A single injection of 25 mg / kg of Benzilylcholine Mustard to living mice resulted in 90 % irreversible block of brain M-receptors. The time course of the receptor density was then monitored by 3H-QNB binding assay and the production rate and turnover rate constant were calculated from the time course curve with a computer program. It was found that in normal mice the turnover rate constant was about 0.035 h-1 (half-life was about 20 h) and the production rate was 30-42 fmol / (h · mg protein). Parallel experiments revealed a significant slow down of the turnover of brain M-receptors in hypothyroid mice (turnover rate constant was 0.0257±0.0012 h-1 in hypothyroid vs. 0.0356 ± 0.0021 h-1 in normal) while the production rate was not changed significantly. The results suggest that thyroid hormones have a regulatory action on the turnover of brain M-receptors and the elevation of brain M-receptor density together with slow down of the turnover of brain M-receptors is probably one of the important mechanisms relevant to the brain dysfunction in hypothyroidism.
keywordHypothyroidism;Muscarinic cholinergic receptor;Benzilylcholine mustard (BCM);Metabolic kinetics of M-receptor;Brain M-receptor;
Research article 01 Nov 1993
Zhu Shengyun,Li Anli,Zheng Shengnan,Shi Suolang,Gou Zhenhui,Li Donghong,Huang Hanchen
The heavy ion irradiation is used for the first time to simulate the radiation damage produced by reactor neutrons in home-made modified stainless steels. The produced radiation damage is investigated by the positron annihilation spectroscopy. No detectable radiation damage is observed in the home-made modified stainless steels irradiated by 81.6 MeV carbon ions to a total dose of 3.3 × 1016 cm-2, indicating that the home-made modified stainless steel of this type has good radiation resistant properties.
keywordModified stainless steel;Radiation damage;Radiation resistant property;Heavy ion simulation;Positron annihilation lifetime;
Research article 01 Nov 1993
Li Zhengkui,Zhang Bosen,You Jingjing
In this paper, various kinds of monomers 2-hydroxyethyl methacrylate (HEMA). 2-hydroxyethyl acrylate (HEA), hydroxypropyl methacrylate (HPMA) and methoxy polyethylene glycol methylacrylate (M-23G) were copolymerized by radiation technique at low temperature (-78℃) and several kinds of copolymer carriers were obtained. Yeast cells were immobilized through adhesion and multiplication of yeast cells themselves on these carriers. The ethanol productivity of immobilized yeast cells with these carriers was related to the monomer composition and water content of copolymer carriers and the optimum monomer composition was 20%:10% in poly (HEA-M23G). In this case, the ethanol productivity of immobilized yeast cells was 26 mg/( ml·h), which was 4 times as high as that of free cells. In this study, the effect of adding of crosslinking reagent (4G) in copolymer on activity of yeast cells immobilized with the carriers were also studied. It was found that the effect of adding crosslinking reagent (4G) in lower monomer composition of poly(HEA-M23G) on the ethanol productivity of immobilized cells was better than that in higher one in this work.
keywordEthanol productivity;Yeast cells;Immobilization;Radiation Copolymer;
Research article 01 Nov 1993
Jin Changwen,Lu Xiting,Huang Xiaojing,Ye Yanlin,Jiang Dongxing,Liu Hongtao,Xia Zonghuang
With the method of Rutherford backscattering of heavy ions from heavy substrate, the stopping powers of 11B, 12C and 19F in silver film were measured at energies from 0.11-0.53 MeV / u. The results are compared with the previous experimental data and the semiempirical calculations of TRIM-90.
keywordRBS;Stopping power;Heavy ions;
Research article 01 Nov 1993
Wang Jie,Huang Guanglin
In this paper Al2O3 and MgO were studied as targets for the radiation grafting of MAA by electron beams. The reaction conditions and materials were characterized by IR spectroscopy, Scanning electron microscopy, X-ray diffraction methods. It is concluded that grafting copolymerization of inorganic oxides and organic monomers has been confirmed. We focus our attention on using ESR spectrum to study the effects of ionizing radiation on inorganic oxides and the properties of initiating active centers. In addition, the radiation grafting mechanism of inorganic oxides and organic monomers has been primarily investigated.
keywordAluminum oxide;Magnesium oxide;Methacrylic acid;Radiation grafting;ESR spectrum;
Research article 01 Nov 1993
Feng Gensheng,Li Hanyin
According to the requirements of improving production of 241Am source used for smoke-sensitice fire alarm making, a method and equipment of its fast relative calibration have been developed. Six measuring equipments have being successfully applied at production lines of 241Am fire alarm source and factories of automatic smoke-sensitive fire alarm making.
keyword241Am fire alarm source;α particle emission rate;Relative calibration;